Half-sandwich ruthenium(II) and iridium(III) complexes of imidazole based phosphinite ligands: antioxidant and antibacterial activities as well as electrochemical properties

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dc.authorid0000-0001-8028-2244en_US
dc.authorid0000-0002-5505-2700en_US
dc.authorid0000-0002-5505-2700en_US
dc.authorid0000-0003-0899-1948en_US
dc.authorid0000-0001-5700-8546en_US
dc.authorid0000-0002-4238-5012en_US
dc.contributor.authorIşık, Uğur
dc.contributor.authorRafikova, Khadichakhan
dc.contributor.authorMeriç, Nermin
dc.contributor.authorGüzel, Remziye
dc.contributor.authorKerimkulova, Aygül
dc.contributor.authorAkimbek, Arailym
dc.contributor.authorOkumuş, Veysi
dc.contributor.authorDurap, Feyyaz
dc.contributor.authorKayan, Cezmi
dc.contributor.authorAydemir, Murat
dc.date.accessioned2024-04-15T11:55:05Z
dc.date.available2024-04-15T11:55:05Z
dc.date.issued2024en_US
dc.departmentDicle Üniversitesi, Fen Fakültesi, Kimya Bölümüen_US
dc.description.abstractRuthenium(II) and iridium(III) complexes of phosphinites including imidazole moiety were synthesized and characterized by microanalysis, IR, MS, and NMR spectroscopies. Antibacterial activity against Gram-positive and Gram-negative bacterial strains was assessed in all complexes. The highest radical scavenging (72.2 %) was obtained for [3-(3-chloro-2-({[dichloro(η6-benzene)ruthenium]diphenylphosphanyl}oxy)propyl)-1-butyl-1H-imidazol-3-ium chloride], 4 at 200 μg/mL concentration, while [3-(3-chloro-2-({[dichloro(η5-pentamethylcyclopentadienyl)-iridium]diphenylphosphanyl}oxy)pro-pyl)-1-butyl-1H-imidazol-3-ium chloride], 6 demonstrated the highest antibacterial activity as 13 mm inhibition zone against E. hirea. Furthermore, optical and electrochemical featured of metal complexes containing imidazole phosphinite were investigated utilizing UV–vis absorption and cyclic voltammetry techniques. Consequently, all complexes can be proposed as metal-based charge convertible phosphinite complexes which may be employed as new generation and synergistic Dye-Sensitized Solar Cell (DSSC) materials.en_US
dc.identifier.citationIşık, U., Rafikova, K., Meriç, N., Güzel, R., Kerimkulova, A., Akimbek, A. ve diğerleri. (2024). Half-sandwich ruthenium(II) and iridium(III) complexes of imidazole based phosphinite ligands: antioxidant and antibacterial activities as well as electrochemical properties. ChemistrySelect, 9(6), 1-12.en_US
dc.identifier.doi10.1002/slct.202304785
dc.identifier.endpage12en_US
dc.identifier.issn2365-6549
dc.identifier.issue6en_US
dc.identifier.scopus2-s2.0-85184711433
dc.identifier.scopusqualityQ3
dc.identifier.startpage1en_US
dc.identifier.urihttps://chemistry-europe.onlinelibrary.wiley.com/doi/epdf/10.1002/slct.202304785
dc.identifier.urihttps://hdl.handle.net/11468/13867
dc.identifier.volume9en_US
dc.identifier.wosWOS:001159911900004
dc.identifier.wosqualityN/A
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.institutionauthorMeriç, Nermin
dc.institutionauthorDurap, Feyyaz
dc.institutionauthorKayan, Cezmi
dc.institutionauthorAydemir, Murat
dc.language.isoenen_US
dc.publisherJohn Wiley and Sons Incen_US
dc.relation.ispartofChemistrySelect
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectAntibacterial/Biological studyen_US
dc.subjectElectrochemical propertiesen_US
dc.subjectImidazolium salten_US
dc.subjectIonic liquiden_US
dc.subjectPhosphinite liganden_US
dc.subjectTransition metalen_US
dc.titleHalf-sandwich ruthenium(II) and iridium(III) complexes of imidazole based phosphinite ligands: antioxidant and antibacterial activities as well as electrochemical propertiesen_US
dc.titleHalf-sandwich ruthenium(II) and iridium(III) complexes of imidazole based phosphinite ligands: antioxidant and antibacterial activities as well as electrochemical properties
dc.typeArticleen_US

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