Synthesis and characterizations of N,N′-bis(diphenylphosphino)-2-(aminomethyl)aniline derivatives: application of a palladium(II) complex as pre-catalyst in Heck and Suzuki cross-coupling reactions

Basit Öğe Kaydı
dc.contributor.authorAydemir, Murat
dc.contributor.authorBaysal, Akın
dc.contributor.authorÖztürk, Gülşen
dc.contributor.authorGümgüm, Bahattin
dc.contributor.orcid0000-0001-7294-6792
dc.date.accessioned2024-04-24T15:59:18Z
dc.date.available2024-04-24T15:59:18Z
dc.date.issued2009
dc.departmentDicle Üniversitesi, Fen Fakültesi, Kimya Bölümüen_US
dc.description.abstractThe reaction of 2-(aminomethyl)aniline with 2 equivalents of PPh2Cl in the presence of Et3N, proceeds in CH2Cl2 to give N,N'-bis(diphenyl phosphino)-2-(aminomethyl)ani line 1 in good yield. Oxidation of 1 with aqueous H2O2, elemental sulfur or gray selenium gave the corresponding oxide, sulfide and selenide dichalcogenides [Ph2P(E)NHC6H4CH2NHP(E)Ph-2] (E: O, 2a; S, 2b; Se, 2c), respectively. The reaction of [Ph2PNHC6H4CH2NHPPh2] with PdCl2(cod), PtCl2(cod) and [Cu(MeCN)(4)]PF6 gave the corresponding chelate complexes, PdCl(2)1, PtCl(2)1 and [Cu(1)(2)]PF6. The new compounds were fully characterized by NMR, IR spectroscopy and elemental analysis. The catalytic activity of the Pd(II) complex was tested in the Suzuki coupling and Heck reactions. The Pd(II) complex catalyzes the Suzuki coupling and Heck reaction, affording biphenyls and stilbenes respectively, in good yields. Copyright (c) 2008 John Wiley & Sons, Ltd.en_US
dc.description.sponsorshipDicle University Research fund (DUAPK) [DUAPK-05-FF-27]en_US
dc.description.sponsorshipWe would like to thank to the Dicle University Research fund (DUAPK) for financial support under project number DUAPK-05-FF-27.en_US
dc.identifier.citationAydemir, M., Baysal, A., Öztürk, G. ve Gümgüm, B. (2009). Synthesis and characterizations of N,N′-bis(diphenylphosphino)-2-(aminomethyl)aniline derivatives: application of a palladium(II) complex as pre-catalyst in Heck and Suzuki cross-coupling reactions. Applied Organometallic Chemistry, 23(3), 108-113.
dc.identifier.doi10.1002/aoc.1477
dc.identifier.endpage113en_US
dc.identifier.issn0268-2605
dc.identifier.issn1099-0739
dc.identifier.issue3en_US
dc.identifier.scopus2-s2.0-61849163800
dc.identifier.scopusqualityQ1
dc.identifier.startpage108en_US
dc.identifier.urihttps://doi.org/10.1002/aoc.1477
dc.identifier.urihttps://hdl.handle.net/11468/13954
dc.identifier.urihttps://onlinelibrary.wiley.com/doi/epdf/10.1002/aoc.1477
dc.identifier.volume23en_US
dc.identifier.wosWOS:000263889600002
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.institutionauthorAydemir, Murat
dc.institutionauthorBaysal, Akın
dc.institutionauthorÖztürk, Gülşen
dc.institutionauthorGümgüm, Bahattin
dc.language.isoenen_US
dc.publisherWileyen_US
dc.relation.ispartofApplied Organometallic Chemistry
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectBis(Diphenylphosphinoamino) Ligandsen_US
dc.subjectPalladiumen_US
dc.subjectPlatinumen_US
dc.subjectCopperen_US
dc.subjectSuzuki reactionen_US
dc.subjectHeck reactionen_US
dc.titleSynthesis and characterizations of N,N′-bis(diphenylphosphino)-2-(aminomethyl)aniline derivatives: application of a palladium(II) complex as pre-catalyst in Heck and Suzuki cross-coupling reactionsen_US
dc.titleSynthesis and characterizations of N,N?-bis(diphenylphosphino)-2-(aminomethyl)aniline derivatives: application of a palladium(II) complex as pre-catalyst in Heck and Suzuki cross-coupling reactions
dc.typeArticleen_US

Dosyalar

Orijinal paket
Listeleniyor 1 - 1 / 1
[ X ]
İsim:
Synthesis and characterizations of N,N′-bis(diphenylphosphino)-2-(aminomethyl)aniline derivatives application of a palladium(II) complex as pre-catalyst in Heck and Suzuki cross-coupling reactions.pdf
Boyut:
169.07 KB
Biçim:
Adobe Portable Document Format
Açıklama:
Makale Dosyası
İndir

Koleksiyon

WoS İndeksli Yayınlar Koleksiyonu
Kimya Bölümü Koleksiyonu
Scopus İndeksli Yayınlar Koleksiyonu