New Pd(II) and Pt(II)-diaminophosphine complexes bearing cyclohexyl or isopropyl moiety: use of Pd(II) complexes as precatalyst in Mizoroki-Heck and Suzuki-Miyaura cross-coupling reactions

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dc.contributor.authorAydemir, Murat
dc.contributor.authorDurap, Feyyaz
dc.contributor.authorBaysal, Akin
dc.date.accessioned2024-04-24T17:21:04Z
dc.date.available2024-04-24T17:21:04Z
dc.date.issued2015
dc.departmentDicle Üniversitesien_US
dc.description.abstractTwo new diaminophosphine ligands, N,N'-bis(dicyclohexylphosphino)-2-(aminomethyl)aniline (1) and N,N'-bis(diisopropylphosphino)-2-(aminomethyl)aniline (2) were synthesized by the reaction of 2-(aminomethyl)aniline with two equivalents of Cy2PCl or (iPr)(2)PCl, respectively. The reactions of 1 and 2 with MCl2 (cod) (M = Pd, Pt; cod = 1,5-cyclooctadiene) yield complexes [cis-Pd(L2PNHC6H4CH2NHPL2)Cl-2] (L = Cy 3, iPr 4) and [cisPt(L2PNHC6H4CH2NHPL2)Cl-2] (L = Cy 5, iPr 6), respectively. The catalytic activity of the palladium complexes was investigated in the Suzuki-Miyaura cross-coupling reaction in the presence of Cs2CO3 as a base. The palladium complexes were also found to be highly active catalysts in the Mizoroki Heck reaction.en_US
dc.description.sponsorshipDicle University Research fund (DUBAP) [14 FF 78]en_US
dc.description.sponsorshipWe would like to thank Dicle University Research fund (DUBAP) for financial support under project number 14 FF 78.en_US
dc.identifier.doi10.3906/kim-1506-20
dc.identifier.endpage+en_US
dc.identifier.issn1300-0527
dc.identifier.issue6en_US
dc.identifier.scopus2-s2.0-84983212484en_US
dc.identifier.scopusqualityQ3en_US
dc.identifier.startpage1279en_US
dc.identifier.urihttps://doi.org/10.3906/kim-1506-20
dc.identifier.urihttps://hdl.handle.net/11468/19359
dc.identifier.volume39en_US
dc.identifier.wosWOS:000365507600014
dc.identifier.wosqualityQ3
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoenen_US
dc.publisherTubitak Scientific & Technological Research Council Turkeyen_US
dc.relation.ispartofTurkish Journal of Chemistryen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.subjectDiaminophosphineen_US
dc.subjectPalladiumen_US
dc.subjectPlatinumen_US
dc.subjectSuzuki Reactionen_US
dc.subjectHeck Reactionen_US
dc.subjectStilbeneen_US
dc.titleNew Pd(II) and Pt(II)-diaminophosphine complexes bearing cyclohexyl or isopropyl moiety: use of Pd(II) complexes as precatalyst in Mizoroki-Heck and Suzuki-Miyaura cross-coupling reactionsen_US
dc.typeArticleen_US

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