Ferrocene based chiral binuclear η6-benzene-Ru(II)-phosphinite complexes: Synthesis, characterization and catalytic activity in asymmetric reduction of ketones

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dc.contributor.authorAl-bayati, Yaser W. Abdlhmed
dc.contributor.authorKarakaş, Duygu Elma
dc.contributor.authorMeriç, Nermin
dc.contributor.authorAydemir, Murat
dc.contributor.authorDurap, Feyyaz
dc.contributor.authorBaysal, Akın
dc.contributor.orcid0000-0001-7294-6792
dc.contributor.orcid0000-0003-0899-1948
dc.contributor.orcid0000-0003-2582-9993
dc.date.accessioned2024-04-24T15:59:19Z
dc.date.available2024-04-24T15:59:19Z
dc.date.issued2018
dc.departmentDicle Üniversitesi, Fen Fakültesi, Kimya Bölümüen_US
dc.description.abstractIn the present study, a series of chiral C-2-symmetric ferrocenyl based binuclear (6)-benzene-Ru(II) complexes bearing diphenylphosphinite and diisopropylphosphinite moieties have been synthesised. The new binuclear (6)-benzene-Ru(II)-phosphinite complexes were characterised based on nuclear magnetic resonance (H-1, C-13, P-31-NMR), FT-IR spectroscopy and elemental analysis. Then, these complexes have been screened as catalytic precursors in the transfer hydrogenation of acetophenone with 2-propanol as both the hydrogen source and solvent in the presence of KOH. The corresponding optically active secondary alcohols were obtained in excellent conversion rates between 96 and 99% and moderate to good enantioselectivities (up to 78% ee). The complex 5 was the most efficient catalyst among the four new complexes investigated herein.en_US
dc.description.sponsorshipResearch Fund of Dicle University [DUBAP-FEN.15.023, DUBAP-FEN.16.008, DUBAP-FEN.16.010]en_US
dc.description.sponsorshipResearch Fund of Dicle University, Grant/ Award Number: (DUBAP-FEN.15.023, DUBAP-FEN.16.008 and DUBAP-FEN.16.010)en_US
dc.identifier.citationAl-bayati, Y. W. A., Karakaş, D. E., Meriç, N., Aydemir, M., Durap, F. ve Baysal, A. (2018). Ferrocene based chiral binuclear η6-benzene-Ru(II)-phosphinite complexes: Synthesis, characterization and catalytic activity in asymmetric reduction of ketones. Applied Organometallic Chemistry, 32(1), 1-10.
dc.identifier.doi10.1002/aoc.3919
dc.identifier.endpage10
dc.identifier.issn0268-2605
dc.identifier.issn1099-0739
dc.identifier.issue1en_US
dc.identifier.scopus2-s2.0-85038425196
dc.identifier.scopusqualityQ1
dc.identifier.startpage1
dc.identifier.urihttps://doi.org/10.1002/aoc.3919
dc.identifier.urihttps://hdl.handle.net/11468/13971
dc.identifier.urihttps://onlinelibrary.wiley.com/doi/epdf/10.1002/aoc.3919
dc.identifier.volume32en_US
dc.identifier.wosWOS:000418447500027
dc.identifier.wosqualityQ1
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.institutionauthorAl-bayati, Yaser W. Abdlhmed
dc.institutionauthorKarakaş, Duygu Elma
dc.institutionauthorMeriç, Nermin
dc.institutionauthorAydemir, Murat
dc.institutionauthorDurap, Feyyaz
dc.institutionauthorBaysal, Akın
dc.language.isoenen_US
dc.publisherWileyen_US
dc.relation.ispartofApplied Organometallic Chemistry
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectAsymmetric transfer hydrogenationen_US
dc.subjectCatalysisen_US
dc.subjectChiralen_US
dc.subjectPhosphiniteen_US
dc.subjectRutheniumen_US
dc.titleFerrocene based chiral binuclear η6-benzene-Ru(II)-phosphinite complexes: Synthesis, characterization and catalytic activity in asymmetric reduction of ketonesen_US
dc.titleFerrocene based chiral binuclear ?6-benzene-Ru(II)-phosphinite complexes: Synthesis, characterization and catalytic activity in asymmetric reduction of ketones
dc.typeArticleen_US

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