Ketone transfer hydrogenation reactions catalyzed by catalysts based on a phosphinite ligand

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dc.authorid0000-0001-7294-6792en_US
dc.authorid0000-0003-0456-5124en_US
dc.authorid0000-0001-5700-8546en_US
dc.authorid0000-0003-1010-9563en_US
dc.authorid0000-0003-0899-1948en_US
dc.contributor.authorRafikova, Khadichakhan
dc.contributor.authorBaysal, Akın
dc.contributor.authorMeriç, Nermin
dc.contributor.authorZazybin, Alexey
dc.contributor.authorKayan, Cezmi
dc.contributor.authorIşık, Uğur
dc.contributor.authorDurap, Feyyaz
dc.contributor.authorAydemir, Murat
dc.date.accessioned2023-04-05T13:27:57Z
dc.date.available2023-04-05T13:27:57Z
dc.date.issued2022en_US
dc.departmentDicle Üniversitesi, Fen Fakültesi, Kimya Bölümüen_US
dc.description.abstractReaction of (+/-)-1-(2-furyl) ethanol with an equivalent Ph2PCl in the presence of Et3N proceeds in dry toluene under an argon atmosphere to give 1-(furan-2-yl)ethyl diphenylphosphinite (1) in good yield. Mononuclear complexes [dichloro(eta(6)-p-cymene)(1-furan-2-ylethyl diphenylphosphinite)ruthenium(II)] (2), [dichloro(eta(6)-benzene)(1-furan-2-ylethyl diphenylphosphinite)ruthenium(II)] (3), [chloro(eta(4)-1,5-cyclooctadiene)(1-furan-2-ylethyl diphenylphosphinite)rhodium(I)] (4) and [dichloro(eta(5)-pentamethylcyclopentadienyl)(1-furan-2-ylethyl diphenylphosphinite)iridium(III)] (5) were synthesized and characterized by microanalysis, infrared, MS, and NMR spectroscopies. The complexes are employed as catalysts in transfer hydrogenation of aromatic ketones. The complexes catalyzed reduction of a variety of aromatic ketone substrates bearing electron-withdrawing or donating substituents with very high conversion rates (up to 99%); 5 was the most efficient catalyst for the transfer hydrogenation of ketones.en_US
dc.identifier.citationRafikova, K., Baysal, A., Meriç, N., Zazybin, A., Kayan, C., Işık, U. ve diğerleri. (2022). Ketone transfer hydrogenation reactions catalyzed by catalysts based on a phosphinite ligand. Journal of Coordination Chemistry, 75(3-4), 493-506.en_US
dc.identifier.doi10.1080/00958972.2022.2054339
dc.identifier.endpage506en_US
dc.identifier.issn0095-8972
dc.identifier.issn1029-0389
dc.identifier.issue3-4en_US
dc.identifier.scopus2-s2.0-85131780570
dc.identifier.scopusqualityQ3
dc.identifier.startpage493en_US
dc.identifier.urihttps://www.tandfonline.com/doi/full/10.1080/00958972.2022.2054339
dc.identifier.urihttps://hdl.handle.net/11468/11620
dc.identifier.volume75en_US
dc.identifier.wosWOS:000791132100001
dc.identifier.wosqualityQ3
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.institutionauthorBaysal, Akın
dc.institutionauthorMeriç, Nermin
dc.institutionauthorKayan, Cezmi
dc.institutionauthorIşık, Uğur
dc.institutionauthorDurap, Feyyaz
dc.institutionauthorAydemir, Murat
dc.language.isoenen_US
dc.publisherTaylor & Francisen_US
dc.relation.ispartofJournal of Coordination Chemistry
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectTransfer hydrogenationen_US
dc.subjectIridiumen_US
dc.subjectKetoneen_US
dc.subjectPhosphinite liganden_US
dc.subjectTransition metalen_US
dc.titleKetone transfer hydrogenation reactions catalyzed by catalysts based on a phosphinite liganden_US
dc.titleKetone transfer hydrogenation reactions catalyzed by catalysts based on a phosphinite ligand
dc.typeArticleen_US

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