Synthesis and spectral characterization of macrocyclic Schiff base by reaction of 2,6-diaminopyridine and 1,4-bis(2-carboxyaldehydephenoxy)butane and its CuII, NiII, PbII, CoIII and LaIII complexes

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dc.contributor.authorIlhan, Salih
dc.contributor.authorTemel, Hamdi
dc.contributor.authorZiyadanogullari, Recep
dc.contributor.authorSekerci, Memet
dc.date.accessioned2024-04-24T16:02:22Z
dc.date.available2024-04-24T16:02:22Z
dc.date.issued2007
dc.departmentDicle Üniversitesien_US
dc.description.abstractA new macrocyclic ligand, 1,3,5-triaza-2,4:7,8:15,16-tribenzo-9,15-dioxacycloheptadeca-1,5-diene (L) was synthesized by reaction of 2,6-diaminopyridine with 1,4-bis(2-carboxyaldehydephenoxy)butane. Then, its Cu-II, Ni-II, Pb-II,and Co-III and La-III complexes were synthesized by the template effect by reaction of 2,6-diaminopyridine and 1,4-bis(2-carboxyaldehydephenoxy)butane and Cu(NO3)(2)center dot 3H(2)O, Ni(NO3)(2) center dot 6H(2)O, Pb(NO3)(2), Co(NO3)(2) center dot 6H(2)O, La(NO3)(3) center dot 6H(2)O, respectively. The ligand and its metal complexes were characterized by elemental analysis, IR, H-1- and C-13-n.m.r., UV-vis spectra, magnetic susceptibility, thermal gravimetric analysis, conductivity measurements and mass spectra. All complexes are diamagnetic and the Cu-II complex is binuclear. The Co-II complex was oxidised to Co-III.en_US
dc.identifier.doi10.1007/s11243-007-0217-3
dc.identifier.endpage590en_US
dc.identifier.issn0340-4285
dc.identifier.issn1572-901X
dc.identifier.issue5en_US
dc.identifier.scopus2-s2.0-34547226246
dc.identifier.scopusqualityQ2
dc.identifier.startpage584en_US
dc.identifier.urihttps://doi.org/10.1007/s11243-007-0217-3
dc.identifier.urihttps://hdl.handle.net/11468/14764
dc.identifier.volume32en_US
dc.identifier.wosWOS:000248116900006
dc.identifier.wosqualityQ3
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoenen_US
dc.publisherSpringeren_US
dc.relation.ispartofTransition Metal Chemistry
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subject[No Keyword]en_US
dc.titleSynthesis and spectral characterization of macrocyclic Schiff base by reaction of 2,6-diaminopyridine and 1,4-bis(2-carboxyaldehydephenoxy)butane and its CuII, NiII, PbII, CoIII and LaIII complexesen_US
dc.titleSynthesis and spectral characterization of macrocyclic Schiff base by reaction of 2,6-diaminopyridine and 1,4-bis(2-carboxyaldehydephenoxy)butane and its CuII, NiII, PbII, CoIII and LaIII complexes
dc.typeArticleen_US

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