Synthesis and Characterization of Novel Thiourea Derivatives and Their Nickel and Copper Complexes

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dc.contributor.authorBinzet, Gun
dc.contributor.authorKavak, Gulten
dc.contributor.authorKulcu, Nevzat
dc.contributor.authorOzbey, Suheyla
dc.contributor.authorFloerke, Ulrich
dc.contributor.authorArslan, Hakan
dc.date.accessioned2024-04-24T17:12:10Z
dc.date.available2024-04-24T17:12:10Z
dc.date.issued2013
dc.departmentDicle Üniversitesien_US
dc.description.abstractNew benzoyl thiourea derivatives and their nickel and copper complexes were synthesized. The structure of the synthesized compounds were confirmed by elemental analysis, FT-IR, and H-1 NMR techniques. Four of the synthesized compounds are analyzed by X-ray single crystal diffraction technique. Whereas N,N-dimethyl-N'-(4-fluorobenzoyl) thiourea, N, N-diethyl-N'-(4-fluorobenzoyl)thiourea, and N,N-di-n-butyl-N'-(4-fluorobenzoyl)thiourea crystallize in the monoclinic system, bis(N,N-di-n-propyl-N'-(4-fluorobenzoyl)thioureato) nickel(II) complex crystallizes in the triclinic system. These ligandmolecules formdimers through strong intermolecular hydrogen bonds such as N-H center dot center dot center dot S, C-H center dot center dot center dot, and N-H center dot center dot center dot O. Moreover, there are different types of intramolecular interactions in the crystal structures. Bis(N,N-dimethyl-N'-(4-fluorobenzoyl)thioureato) nickel(II) complex has a nearly square-planar coordination. The distance of nickel atom from the best plane through the coordination sphere is 0.029 angstrom.en_US
dc.description.sponsorshipMersin University [BAP-FBE KB (GB) 2006-1 DR]en_US
dc.description.sponsorshipThis study is a part of Gun Binzet's Ph.D. thesis and was supported by Mersin University Research Fund (Project no. BAP-FBE KB (GB) 2006-1 DR).en_US
dc.identifier.doi10.1155/2013/536562
dc.identifier.issn2090-9063
dc.identifier.issn2090-9071
dc.identifier.scopus2-s2.0-84884876857
dc.identifier.scopusqualityQ2
dc.identifier.urihttps://doi.org/10.1155/2013/536562
dc.identifier.urihttps://hdl.handle.net/11468/17879
dc.identifier.volume2013en_US
dc.identifier.wosWOS:000324423000001
dc.identifier.wosqualityQ4
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoenen_US
dc.publisherHindawi Ltden_US
dc.relation.ispartofJournal of Chemistry
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.subject[No Keyword]en_US
dc.titleSynthesis and Characterization of Novel Thiourea Derivatives and Their Nickel and Copper Complexesen_US
dc.titleSynthesis and Characterization of Novel Thiourea Derivatives and Their Nickel and Copper Complexes
dc.typeArticleen_US

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