Synthesis of Lead(II) Minoxidil Coordination Polymer: A New Precursor for Lead(II) Oxide and Lead(II) Hydroxyl Bromide

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dc.contributor.authorRanjbar, Maryam
dc.contributor.authorCelik, Omer
dc.contributor.authorNajafi, S. Heydar Mahmoudi
dc.contributor.authorSheshmani, Shabnam
dc.contributor.authorMobarakeh, Neda Akbari
dc.date.accessioned2024-04-24T16:02:15Z
dc.date.available2024-04-24T16:02:15Z
dc.date.issued2012
dc.departmentDicle Üniversitesien_US
dc.description.abstractA new lead(II) coordination polymer, [PbBr2(C9H15N5O)](n) (1), where C9H15N5O is (2,4-diamino-6-piperidine-1-yl) pyrimidine N-oxide (minoxidil) is synthesized and characterized. Polymer 1 is synthesized in methanol by sonochemical and hydrothermal methods from lead(II) acetate, KBr and the minoxidil ligand. The crystal structure of [PbBr2(C9H15N5O)](n) indicates a syndiotactic coordination polymer. The Pb(II) atom lies on a mirror plane; the mirror plane is perpendicular to the pyrimidine ring bisecting the piperidine ring. N-H center dot center dot center dot O intramolecular and C-H center dot center dot center dot Br, N-H center dot center dot center dot N strong intermolecular interactions were observed. Micro-rods of PbO and nano-plates of PbOHBr were prepared by thermal decomposition of the nano-structured [PbBr2(C9H15N5O)](n) as a precursor. Characterization of the products was carried out using X-ray crystallography, elemental analysis, FTIR spectroscopy, scanning electron microscopy, energy dispersive X-ray analysis and thermal analysis. The sonochemical method resulted in a significant reduction of reaction time, reaction temperature and particle sizes of the products.en_US
dc.description.sponsorshipnanotechnology initiative council [89118]; Iranian Research Organization for Science and Technologyen_US
dc.description.sponsorshipThe authors would like to express gratitude for support by nanotechnology initiative council (Project Number 89118) and for financial assistance by Iranian Research Organization for Science and Technology. The authors are indebted to Anadolu University and the Medicinal Plants and Medicine Research Centre of Anadolu University, Eskisehir, Turkey, for the use of X-ray diffractometer.en_US
dc.identifier.doi10.1007/s10904-011-9648-6
dc.identifier.endpage844en_US
dc.identifier.issn1574-1443
dc.identifier.issn1574-1451
dc.identifier.issue4en_US
dc.identifier.scopus2-s2.0-84862647353
dc.identifier.scopusqualityQ1
dc.identifier.startpage837en_US
dc.identifier.urihttps://doi.org/10.1007/s10904-011-9648-6
dc.identifier.urihttps://hdl.handle.net/11468/14709
dc.identifier.volume22en_US
dc.identifier.wosWOS:000305224400020
dc.identifier.wosqualityQ3
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoenen_US
dc.publisherSpringeren_US
dc.relation.ispartofJournal of Inorganic and Organometallic Polymers and Materials
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectMinoxidilen_US
dc.subjectCoordination Polymeren_US
dc.subjectSonochemistryen_US
dc.subjectLead(Ii) Nano-Structuresen_US
dc.titleSynthesis of Lead(II) Minoxidil Coordination Polymer: A New Precursor for Lead(II) Oxide and Lead(II) Hydroxyl Bromideen_US
dc.titleSynthesis of Lead(II) Minoxidil Coordination Polymer: A New Precursor for Lead(II) Oxide and Lead(II) Hydroxyl Bromide
dc.typeArticleen_US

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