The novel pyridine based symmetrical Schiff base ligand and its transition metal complexes: synthesis, spectral definitions and application in dye sensitized solar cells (DSSCs)

Basit Öğe Kaydı
dc.contributor.authorImer, Arife Gencer
dc.contributor.authorSyan, Ranjdar Hamad Basha
dc.contributor.authorGulcan, Mehmet
dc.contributor.authorOcak, Yusuf Selim
dc.contributor.authorTombak, Ahmet
dc.date.accessioned2024-04-24T16:02:14Z
dc.date.available2024-04-24T16:02:14Z
dc.date.issued2018
dc.departmentDicle Üniversitesien_US
dc.description.abstractThe pyridine based azo-linked symmetrical Schiff base ligand, (E)-2,2'-((1E,1'E)-(pyridine-2,6-diylbis(azanylylidene))bis(methanylylidene))bis(4-((E)-phenyldiazenyl)phenol) (H2L), and its Co(II), Ni(II) and Pd(II) transition metal complexes were prepared, and defined by using elemental analysis, Fourier transform infrared, UV-visible, mass, nuclear magnetic resonance spectra, molar conductance, magnetic susceptibility and thermal analysis techniques. The conductivity results pointed out the non-electrolytic nature of all metal complexes. Elemental composition, ultraviolet spectra and magnetic susceptibility data showed that the synthesized complexes are in the binuclear structure and square plane geometry. When compared to the characteristic infrared bands for the functional groups of the ligand structure with complex molecules are reached, the ligand binds to the metal atom via phenolic OH and azomethine-nitrogen. Furthermore, the dye-sensitized solar cells (DSSCs) based on H2L and its metal complexes were fabricated, and photovoltaic properties of these devices were also investigated. The power conversion efficiency of fabricated devices based on ligand H2L can be improved with the incorporation of the transition metal complex.en_US
dc.description.sponsorshipPresidency of Scientific Research Projects of University of Van Yuzuncu Yil [FAP-2016-5619]; Presidency of Scientific Research and Technological Application Center of Dicle Universityen_US
dc.description.sponsorshipAuthors wish to thank the Presidency of Scientific Research Projects of University of Van Yuzuncu Yil (the Project Number FAP-2016-5619); and Presidency of Scientific Research and Technological Application Center of Dicle University for their supports.en_US
dc.identifier.doi10.1007/s10854-017-7986-z
dc.identifier.endpage905en_US
dc.identifier.issn0957-4522
dc.identifier.issn1573-482X
dc.identifier.issue2en_US
dc.identifier.scopus2-s2.0-85030844984
dc.identifier.scopusqualityQ2
dc.identifier.startpage898en_US
dc.identifier.urihttps://doi.org/10.1007/s10854-017-7986-z
dc.identifier.urihttps://hdl.handle.net/11468/14700
dc.identifier.volume29en_US
dc.identifier.wosWOS:000422863600005
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoenen_US
dc.publisherSpringeren_US
dc.relation.ispartofJournal of Materials Science-Materials in Electronics
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subject[No Keyword]en_US
dc.titleThe novel pyridine based symmetrical Schiff base ligand and its transition metal complexes: synthesis, spectral definitions and application in dye sensitized solar cells (DSSCs)en_US
dc.titleThe novel pyridine based symmetrical Schiff base ligand and its transition metal complexes: synthesis, spectral definitions and application in dye sensitized solar cells (DSSCs)
dc.typeArticleen_US

Dosyalar

Koleksiyon

WoS İndeksli Yayınlar Koleksiyonu
Scopus İndeksli Yayınlar Koleksiyonu