Investigation of the arsenic(V) retention performance of the nano-sorbent (M-TACA) synthesized by click chemistry

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dc.authorid0000-0001-7555-2481en_US
dc.authorid0000-0002-0325-1257en_US
dc.authorid0000-0003-2479-9438en_US
dc.contributor.authorTural, Bilsen
dc.contributor.authorErtaş, Erdal
dc.contributor.authorTural, Servet
dc.date.accessioned2022-03-10T06:58:37Z
dc.date.available2022-03-10T06:58:37Z
dc.date.issued2022en_US
dc.departmentDicle Üniversitesi, Ziya Gökalp Eğitim Fakültesi, Matematik ve Fen Bilimleri Eğitimi Bölümüen_US
dc.descriptionWOS:000760083000001
dc.description.abstractIn this study N-methyl-D-glucamine selective functional group is bound to magnetic nanoparticles (M-TACA) with click chemistry, which is fast, simple to use, easy to purify, versatile, region-specific and gives high product yield. The synthesized M-TACA nano-sorbent was characterized by SEM and VSM techniques. The parameters effecting sorption of As(V) onto M-TACA such as dosage, initial concentration of As(V), contact time and pH were studied. Sorption of As(V) onto M-TACA nano-sorbent is pH dependent and the maximum sorption capacity was obtained at pH 6 as 76.54 +/- 1.21 mg/g. The effects of fluoride, sulfate and phosphate ions, which compete with As(V) to hold active groups, on the sorption of As(V) were investigated. Fluoride has minimal effect on arsenic uptake. It is sulfate that has the most negative effect on intake and phosphorus has had a less negative effect. Sorption is more compatible with the Langmuir isotherm model than any other applied isotherm model. Results obtained from intra particle diffusion model shown the two sorption stages indicating that both surface and intra-particle sorption occurs. At the same time, sorption percentages for five times reusability were determined as 99.6 +/- 2.5%, 99.0 +/- 3.0%, 98.6 +/- 3.1%, 97.0 +/- 3.5% and 96.6 +/- 3.8%, respectively. The reusability results showed that the M-TACA nano-sorbent can be reused at least 5 times in removal of As(V).en_US
dc.identifier.citationTural, B., Ertaş, E. ve Tural, S. (2022). Investigation of the arsenic(V) retention performance of the nano-sorbent (M-TACA) synthesized by click chemistry. Journal of Dispersion Science and Technology, Early Access.en_US
dc.identifier.doi10.1080/01932691.2022.2040529
dc.identifier.issn0193-2691
dc.identifier.issn1532-2351
dc.identifier.scopus2-s2.0-85125836578
dc.identifier.scopusqualityQ2
dc.identifier.urihttps://www.tandfonline.com/doi/full/10.1080/01932691.2022.2040529
dc.identifier.urihttps://hdl.handle.net/11468/9368
dc.identifier.volumeEarly Accessen_US
dc.identifier.wosWOS:000760083000001
dc.identifier.wosqualityQ4
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.institutionauthorTural, Bilsen
dc.institutionauthorErtaş, Erdal
dc.institutionauthorTural, Servet
dc.language.isoenen_US
dc.publisherTaylor & Francisen_US
dc.relation.ispartofJournal of Dispersion Science and Technology
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectClick chemistryen_US
dc.subjectN-methyl-D-glucamineen_US
dc.subjectMagnetic Nano-sorbenten_US
dc.subjectArsenic(V) Removalen_US
dc.subjectIsothermsen_US
dc.subjectKineticsen_US
dc.titleInvestigation of the arsenic(V) retention performance of the nano-sorbent (M-TACA) synthesized by click chemistryen_US
dc.titleInvestigation of the arsenic(V) retention performance of the nano-sorbent (M-TACA) synthesized by click chemistry
dc.typeArticleen_US

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