Investigation of some 1,3-diols for the requirements of solvent extraction of boron: 2,2,6-trimethyl-1,3 heptanediol as a potential boron extractant

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dc.contributor.authorTural, Bilsen
dc.contributor.authorTural, Servet
dc.contributor.authorHosgoren, Halil
dc.date.accessioned2024-04-24T17:37:34Z
dc.date.available2024-04-24T17:37:34Z
dc.date.issued2007
dc.departmentDicle Üniversitesien_US
dc.description.abstractEighteen 1,3-diols were syntesized and their structure and distribution ratio for the solvent extraction of boron were studied. Diols with a high distribution ration (DB(OH)3 > 10) were investigated for the requirements of solvent extraction of boron. Their extraction capacity, and solubility in aqueous phase and in organic diluents were investigated by comparison to 2-ethyl-1,3-hexanediol (EHD), which is widely used as a boron extractant. Among a series of 1,3 diols, 1-benzyl-2,2-dimethyl-1,3-propanediol (4a) and 2,2,6-trimethyl-1,3-heptanediol (3a) were found to have very low solubility in the aqueous phase compared to the others. IPD (3a) was found to have a high solubility in aliphatic diluents such as kerosene. IPD, which has good solubility properties for the solvent extraction of boron, was studied in detail, including dependence of pH, diol concentration, and stripping facility, and in various organic diluents.en_US
dc.identifier.endpage170en_US
dc.identifier.issn1300-0527
dc.identifier.issue2en_US
dc.identifier.scopus2-s2.0-34247545292
dc.identifier.scopusqualityQ3
dc.identifier.startpage163en_US
dc.identifier.urihttps://hdl.handle.net/11468/21034
dc.identifier.volume31en_US
dc.identifier.wosWOS:000246883000007
dc.identifier.wosqualityQ3
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoenen_US
dc.publisherTubitak Scientific & Technological Research Council Turkeyen_US
dc.relation.ispartofTurkish Journal of Chemistry
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subject[No Keyword]en_US
dc.titleInvestigation of some 1,3-diols for the requirements of solvent extraction of boron: 2,2,6-trimethyl-1,3 heptanediol as a potential boron extractanten_US
dc.titleInvestigation of some 1,3-diols for the requirements of solvent extraction of boron: 2,2,6-trimethyl-1,3 heptanediol as a potential boron extractant
dc.typeArticleen_US

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