Synthesis, characterization and first application of chiral C2-symmetric bis(phosphinite)-Pd(II) complexes as catalysts in asymmetric intermolecular Heck reactions

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dc.contributor.authorKarakaş, Duygu Elma
dc.contributor.authorDurap, Feyyaz
dc.contributor.authorAydemir, Murat
dc.contributor.authorBaysal, Akın
dc.contributor.orcid0000-0003-2582-9993
dc.contributor.orcid0000-0001-7294-6792
dc.contributor.orcid0000-0003-0899-1948
dc.date.accessioned2024-04-24T15:59:19Z
dc.date.available2024-04-24T15:59:19Z
dc.date.issued2016
dc.departmentDicle Üniversitesi, Fen Fakültesi, Kimya Bölümüen_US
dc.description.abstractA series of new chiral C-2-symmetric bis(phosphinite) ligands and their palladium(II) complexes have been synthesized and for the first time used as catalysts in the palladium-catalysed asymmetric intermolecular Heck coupling reactions of 2,3-dihydrofuran with iodobenzene or aryl triflate. Under optimized conditions, products were obtained with high conversions and moderate to good enantioselectivities. The new C-2-symmetric bis(phosphinite) ligands and their palladium(II) complexes were characterized using multinuclear NMR and Fourier transform infrared spectroscopies and elemental analysis. Copyright (c) 2015 John Wiley & Sons, Ltd.en_US
dc.description.sponsorshipDicle University Science and Technology Application and Research Center (DUBTAM); Dicle University Research Fund DUBAP [13-FF-114]en_US
dc.description.sponsorshipAnalysis and research were supported by the Dicle University Science and Technology Application and Research Center (DUBTAM) which is gratefully acknowledged. Financial support from Dicle University Research Fund DUBAP (project no. 13-FF-114) is gratefully acknowledged. The authors thank Prof. Dr Yilmaz Turgut (Dicle University) for valuable contributions.en_US
dc.identifier.citationKarakaş, D. E., Durap, F., Aydemir, M. ve Baysal, A. (2016). Synthesis, characterization and first application of chiral C2-symmetric bis(phosphinite)-Pd(II) complexes as catalysts in asymmetric intermolecular Heck reactions. Applied Organometallic Chemistry, 30(4), 193-198.
dc.identifier.doi10.1002/aoc.3416
dc.identifier.endpage198en_US
dc.identifier.issn0268-2605
dc.identifier.issn1099-0739
dc.identifier.issue4en_US
dc.identifier.scopus2-s2.0-84953432819
dc.identifier.scopusqualityQ1
dc.identifier.startpage193en_US
dc.identifier.urihttps://doi.org/10.1002/aoc.3416
dc.identifier.urihttps://hdl.handle.net/11468/13969
dc.identifier.urihttps://onlinelibrary.wiley.com/doi/10.1002/aoc.3416
dc.identifier.volume30en_US
dc.identifier.wosWOS:000372924700004
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.institutionauthorKarakaş, Duygu Elma
dc.institutionauthorDurap, Feyyaz
dc.institutionauthorAydemir, Murat
dc.institutionauthorBaysal, Akın
dc.language.isoenen_US
dc.publisherWiley-Blackwellen_US
dc.relation.ispartofApplied Organometallic Chemistry
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectPalladium(Ii)en_US
dc.subjectC-2 symmetryen_US
dc.subjectPhosphiniteen_US
dc.subjectAsymmetric heck couplingen_US
dc.titleSynthesis, characterization and first application of chiral C2-symmetric bis(phosphinite)-Pd(II) complexes as catalysts in asymmetric intermolecular Heck reactionsen_US
dc.titleSynthesis, characterization and first application of chiral C2-symmetric bis(phosphinite)-Pd(II) complexes as catalysts in asymmetric intermolecular Heck reactions
dc.typeArticleen_US

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