Chiral phosphinites as efficient ligands for enantioselective Ru(II), Rh(I) and Ir(III)-catalyzed transfer hydrogenation reactions
dc.contributor.author | Baysal, Akin | |
dc.contributor.author | Karakas, Duygu Elma | |
dc.contributor.author | Meric, Nermin | |
dc.contributor.author | Ak, Bunyamin | |
dc.contributor.author | Aydemir, Murat | |
dc.contributor.author | Durap, Feyyaz | |
dc.date.accessioned | 2024-04-24T16:02:23Z | |
dc.date.available | 2024-04-24T16:02:23Z | |
dc.date.issued | 2017 | |
dc.department | Dicle Üniversitesi | en_US |
dc.description.abstract | Metal-catalyzed enantioselective transfer reduction of ketones to enantiomerically enriched chiral alcohols has recently attracted attention. Therefore, a series of methyl alkyl or alkyl/aryl ketones have been reduced by using Ru(II), Rh(I) and Ir(III) catalysts based on C (2)-symmetric chiral ferrocenyl phosphinite ligands. The corresponding optically active secondary alcohols were obtained in excellent conversions and moderate-to-good enantioselectivities. The best results were obtained with an iridium catalyst, giving up to 98% conversion and 80% ee. | en_US |
dc.description.sponsorship | TUBITAK [111T419]; Dicle University [FEN.16.010, DUBAP FEN.15.021, FEN.15.022] | en_US |
dc.description.sponsorship | Partial supports of this work by TUBITAK (Project Number: 111T419) and Dicle University (Project Numbers: FEN.16.010 (NMR), DUBAP FEN.15.021 and FEN.15.022) are gratefully acknowledged. | en_US |
dc.identifier.doi | 10.1007/s11243-017-0140-1 | |
dc.identifier.endpage | 372 | en_US |
dc.identifier.issn | 0340-4285 | |
dc.identifier.issn | 1572-901X | |
dc.identifier.issue | 4 | en_US |
dc.identifier.scopus | 2-s2.0-85016482059 | |
dc.identifier.scopusquality | Q2 | |
dc.identifier.startpage | 365 | en_US |
dc.identifier.uri | https://doi.org/10.1007/s11243-017-0140-1 | |
dc.identifier.uri | https://hdl.handle.net/11468/14770 | |
dc.identifier.volume | 42 | en_US |
dc.identifier.wos | WOS:000399456900011 | |
dc.identifier.wosquality | Q3 | |
dc.indekslendigikaynak | Web of Science | |
dc.indekslendigikaynak | Scopus | |
dc.language.iso | en | en_US |
dc.publisher | Springer | en_US |
dc.relation.ispartof | Transition Metal Chemistry | |
dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
dc.rights | info:eu-repo/semantics/closedAccess | en_US |
dc.subject | [No Keyword] | en_US |
dc.title | Chiral phosphinites as efficient ligands for enantioselective Ru(II), Rh(I) and Ir(III)-catalyzed transfer hydrogenation reactions | en_US |
dc.title | Chiral phosphinites as efficient ligands for enantioselective Ru(II), Rh(I) and Ir(III)-catalyzed transfer hydrogenation reactions | |
dc.type | Article | en_US |