Chiral phosphinites as efficient ligands for enantioselective Ru(II), Rh(I) and Ir(III)-catalyzed transfer hydrogenation reactions

Basit Öğe Kaydı
dc.contributor.authorBaysal, Akin
dc.contributor.authorKarakas, Duygu Elma
dc.contributor.authorMeric, Nermin
dc.contributor.authorAk, Bunyamin
dc.contributor.authorAydemir, Murat
dc.contributor.authorDurap, Feyyaz
dc.date.accessioned2024-04-24T16:02:23Z
dc.date.available2024-04-24T16:02:23Z
dc.date.issued2017
dc.departmentDicle Üniversitesien_US
dc.description.abstractMetal-catalyzed enantioselective transfer reduction of ketones to enantiomerically enriched chiral alcohols has recently attracted attention. Therefore, a series of methyl alkyl or alkyl/aryl ketones have been reduced by using Ru(II), Rh(I) and Ir(III) catalysts based on C (2)-symmetric chiral ferrocenyl phosphinite ligands. The corresponding optically active secondary alcohols were obtained in excellent conversions and moderate-to-good enantioselectivities. The best results were obtained with an iridium catalyst, giving up to 98% conversion and 80% ee.en_US
dc.description.sponsorshipTUBITAK [111T419]; Dicle University [FEN.16.010, DUBAP FEN.15.021, FEN.15.022]en_US
dc.description.sponsorshipPartial supports of this work by TUBITAK (Project Number: 111T419) and Dicle University (Project Numbers: FEN.16.010 (NMR), DUBAP FEN.15.021 and FEN.15.022) are gratefully acknowledged.en_US
dc.identifier.doi10.1007/s11243-017-0140-1
dc.identifier.endpage372en_US
dc.identifier.issn0340-4285
dc.identifier.issn1572-901X
dc.identifier.issue4en_US
dc.identifier.scopus2-s2.0-85016482059
dc.identifier.scopusqualityQ2
dc.identifier.startpage365en_US
dc.identifier.urihttps://doi.org/10.1007/s11243-017-0140-1
dc.identifier.urihttps://hdl.handle.net/11468/14770
dc.identifier.volume42en_US
dc.identifier.wosWOS:000399456900011
dc.identifier.wosqualityQ3
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoenen_US
dc.publisherSpringeren_US
dc.relation.ispartofTransition Metal Chemistry
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subject[No Keyword]en_US
dc.titleChiral phosphinites as efficient ligands for enantioselective Ru(II), Rh(I) and Ir(III)-catalyzed transfer hydrogenation reactionsen_US
dc.titleChiral phosphinites as efficient ligands for enantioselective Ru(II), Rh(I) and Ir(III)-catalyzed transfer hydrogenation reactions
dc.typeArticleen_US

Dosyalar

Koleksiyon

WoS İndeksli Yayınlar Koleksiyonu
Scopus İndeksli Yayınlar Koleksiyonu