Novel cyclohexyl-based aminophosphine ligands and use of their Ru(II) complexes in transfer hydrogenation of ketones

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dc.contributor.authorKayan, Cezmi
dc.contributor.authorMeriç, Nermin
dc.contributor.authorAydemir, Murat
dc.contributor.authorOcak, Yusuf Selim
dc.contributor.authorBaysal, Akın
dc.contributor.authorTemel, Hamdi
dc.contributor.orcid0000-0001-7294-6792
dc.contributor.orcid0000-0001-5700-8546
dc.date.accessioned2024-04-24T15:59:19Z
dc.date.available2024-04-24T15:59:19Z
dc.date.issued2014
dc.departmentDicle Üniversitesi, Fen Fakültesi, Kimya Bölümüen_US
dc.description.abstractTwo new aminophosphines - furfuryl-(N-dicyclohexylphosphino)amine, [Cy2PNHCH2-C4H3O] (1) and thiophene-(N-dicyclohexylphosphino)amine, [Cy2PNHCH2-C4H3S] (2) - were prepared by the reaction of chlorodicyclohexylphosphine with furfurylamine and thiophene-2-methylamine. Reaction of the aminophosphines with [Ru((6)-p-cymene)(-Cl)Cl](2) or [Ru((6)-benzene)(-Cl)Cl](2) gave corresponding complexes [Ru(Cy2PNHCH2-C4H3O)((6)-p-cymene)Cl-2] (1a), [Ru(Cy2PNHCH2-C4H3O)((6)-benzene)Cl-2] (1b), [Ru(Cy2PNHCH2-C4H3S)((6)-p-cymene)Cl-2] (2a) and [Ru(Cy2PNHCH2-C4H3S)((6)-benzene)Cl-2] (2b), respectively, which are suitable catalyst precursors for the transfer hydrogenation of ketones. In particular, [Ru(Cy2PNHCH2-C4H3S)((6)-benzene)Cl-2] acts as a good catalyst, giving the corresponding alcohols in 98-99% yield in 30min at 82 degrees C (up to time of flight588h(-1)). Copyright (c) 2014 John Wiley & Sons, Ltd.en_US
dc.identifier.citationKayan, C., Meriç, N., Aydemir, M., Ocak, Y. S., Baysal, A. ve Temel, H. (2014). Novel cyclohexyl-based aminophosphine ligands and use of their Ru(II) complexes in transfer hydrogenation of ketones. Applied Organometallic Chemistry, 28(2), 127-133.
dc.identifier.doi10.1002/aoc.3096
dc.identifier.endpage133en_US
dc.identifier.issn0268-2605
dc.identifier.issn1099-0739
dc.identifier.issue2en_US
dc.identifier.scopus2-s2.0-84893699509
dc.identifier.scopusqualityQ1
dc.identifier.startpage127en_US
dc.identifier.urihttps://doi.org/10.1002/aoc.3096
dc.identifier.urihttps://hdl.handle.net/11468/13963
dc.identifier.urihttps://onlinelibrary.wiley.com/doi/epdf/10.1002/aoc.3096
dc.identifier.volume28en_US
dc.identifier.wosWOS:000331128000013
dc.identifier.wosqualityQ1
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.institutionauthorKayan, Cezmi
dc.institutionauthorAydemir, Murat
dc.institutionauthorOcak, Yusuf Selim
dc.institutionauthorBaysal, Akın
dc.institutionauthorTemel, Hamdi
dc.language.isoenen_US
dc.publisherWileyen_US
dc.relation.ispartofApplied Organometallic Chemistry
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectAminophosphineen_US
dc.subjectRuthenium(Ii)en_US
dc.subjectTransfer hydrogenationen_US
dc.subjectHomogeneous catalysisen_US
dc.titleNovel cyclohexyl-based aminophosphine ligands and use of their Ru(II) complexes in transfer hydrogenation of ketonesen_US
dc.titleNovel cyclohexyl-based aminophosphine ligands and use of their Ru(II) complexes in transfer hydrogenation of ketones
dc.typeArticleen_US

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