Manganese(III) acetate mediated oxidation of 1-alkyl-1H-indole and 9-methyl-9H-carbazole derivatives

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dc.contributor.authorDemir, Ayhan S.
dc.contributor.authorTural, Servet
dc.date.accessioned2024-04-24T17:24:09Z
dc.date.available2024-04-24T17:24:09Z
dc.date.issued2008
dc.departmentDicle Üniversitesien_US
dc.description.abstractManganese(III) acetate mediated oxidation of 1-alkyl-1H-indole and 9-methyl-9H-carbazole was studied. 1-Methyl-1H-indole gives the 1-acetoxymethyl derivative with good yield. 1-Methyl- 2-phenyl-1H-indole furnished the oxidation of the methyl group and C-3 of indole to obtain the corresponding acetoxy derivatives. 1-ethyl-2-phenyl derivative only furnished the C-3 acetoxylation product. 1,2-Dimethyl-1H-indole furnished oxidation on both of the methyl groups. The major products are 1-methyl-1H-indole-2-carbaldehyde and 1-methyl-2diacetoxymethyl- 1H-indole. Manganese(III) acetate oxidation of 9-methyl-9H-carbazole furnished (9H-carbazol-9-yl) methanol in good yield.en_US
dc.description.sponsorshipScientific and Technological Research Council of Turkey (TUBITAK); Turkish Academy of Science (TUBA); Turkish State Planning Organization; Middle East Technical University (METU)en_US
dc.description.sponsorshipThis work was supported by the Scientific and Technological Research Council of Turkey (TUBITAK), the Turkish Academy of Science (TUBA), the Turkish State Planning Organization, and the Middle East Technical University (METU). In particular, S. T. thanks TUBITAK for a postdoctoral fellowship.en_US
dc.identifier.doi10.3998/ark.5550190.0009.d09
dc.identifier.endpage79en_US
dc.identifier.issn1551-7004
dc.identifier.issn1551-7012
dc.identifier.scopus2-s2.0-46849102012en_US
dc.identifier.scopusqualityQ4en_US
dc.identifier.startpage72en_US
dc.identifier.urihttps://doi.org/10.3998/ark.5550190.0009.d09
dc.identifier.urihttps://hdl.handle.net/11468/19453
dc.identifier.wosWOS:000260411300009
dc.identifier.wosqualityQ3
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoenen_US
dc.publisherArkat Usa Incen_US
dc.relation.ispartofArkivocen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.subjectIndoleen_US
dc.subjectCarbazoleen_US
dc.subjectOxidationen_US
dc.subjectManganese(Iii) Acetateen_US
dc.titleManganese(III) acetate mediated oxidation of 1-alkyl-1H-indole and 9-methyl-9H-carbazole derivativesen_US
dc.typeArticleen_US

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