Preparation and spectral characterization of new macrocyclic Ni(II) and Co(II) complexes derived from 1,4-bis(2-carboxyaldehydephenoxy)butane and various diamines

Basit Öğe Kaydı
dc.contributor.authorTemel, H.
dc.contributor.authorIlhan, S.
dc.contributor.authorKilic, A.
dc.contributor.authorTas, E.
dc.date.accessioned2024-04-24T16:24:25Z
dc.date.available2024-04-24T16:24:25Z
dc.date.issued2008
dc.departmentDicle Üniversitesien_US
dc.description.abstractSix new macrocyclic complexes were synthesized by the template effect from reaction of 1,4-bis(2-carboxyaldehydephenoxy)butane, Ni(NO3)(2)center dot 6H(2)O or Co(NO3)(2)center dot 6H(2)O and various diamines. The metal-to-ligand ratios of Ni(II) or Co(II) metal complexes were found to be 1 : 1. Coordination of the Schiff base to Ni(II) and Co(II) through the two nitrogen and two oxygen atom (ONNO) are expected to reduce the electron density in the azomethine link and hydroxyl group. The Ni(II) and Co(II) complexes are proposed to be tetrahedral and are 1 : 2 electrolytes as shown by their molar conductivities (Lambda(M)) in DMF (dimethyl formamide) at 10(-3) M. The structures are proposed from elemental analysis, FT-IR, UV-VIS, magnetic susceptibility measurements, molar conductivity measurements, and mass spectra.en_US
dc.identifier.doi10.1080/00958970701581734
dc.identifier.endpage1454en_US
dc.identifier.issn0095-8972
dc.identifier.issn1029-0389
dc.identifier.issue9en_US
dc.identifier.scopus2-s2.0-45849125014
dc.identifier.scopusqualityQ3
dc.identifier.startpage1443en_US
dc.identifier.urihttps://doi.org/10.1080/00958970701581734
dc.identifier.urihttps://hdl.handle.net/11468/16701
dc.identifier.volume61en_US
dc.identifier.wosWOS:000256805000008
dc.identifier.wosqualityQ3
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoenen_US
dc.publisherTaylor & Francis Ltden_US
dc.relation.ispartofJournal of Coordination Chemistry
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectMacrocyclic Schiff-Base Complexesen_US
dc.subject1,4-Bis(2-Carboxyaldehydephenoxy)Butaneen_US
dc.subjectNickel(Ii) And Co(Ii) Complexesen_US
dc.subjectMass Spectraen_US
dc.titlePreparation and spectral characterization of new macrocyclic Ni(II) and Co(II) complexes derived from 1,4-bis(2-carboxyaldehydephenoxy)butane and various diaminesen_US
dc.titlePreparation and spectral characterization of new macrocyclic Ni(II) and Co(II) complexes derived from 1,4-bis(2-carboxyaldehydephenoxy)butane and various diamines
dc.typeArticleen_US

Dosyalar

Koleksiyon

WoS İndeksli Yayınlar Koleksiyonu
Scopus İndeksli Yayınlar Koleksiyonu