Synthesis, and characterization of palladium(II) and platinum(II) complexes with ?-hydroxy[1-(2-ethoxyethyl) piperidin-4-yl]phosphonate and use of the palladium(II) complex as pre-catalyst in Suzuki-Miyaura cross-coupling reactions

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dc.contributor.authorKystaubayeva, N. U.
dc.contributor.authorDurap, Feyyaz
dc.contributor.authorZharkynbek, T. Y.
dc.contributor.authorYu, V. K.
dc.contributor.authorAydemir, Murat
dc.contributor.authorMeric, Nermin
dc.contributor.authorZazybin, A. G.
dc.date.accessioned2024-04-24T16:15:38Z
dc.date.available2024-04-24T16:15:38Z
dc.date.issued2022
dc.departmentDicle Üniversitesien_US
dc.description.abstractComplexes [MCl2{(L1}2] ( M = Pd, Pt) were obtained by the reaction of the alpha-Hydroxy[1-(2-ethoxyethyl )piperidin-4-yl]phosphonate as ligand with [MCl2(COD)] ( M = Pd, Pt). The new compounds were characterized by NMR and IR spectroscopy, and microanalysis. In addition, representative solid-state structure of the ligand was determined using single crystal X-ray diffraction analysis. Furthermore, ab ini-tio quantum calculations of the ligand and its complexes were also carried out using density functional theory to better understand their chemical behaviors. Finally, the palladium(II) complex of the ligand was tested as a potential catalyst in the Suzuki-Miyaura cross-coupling reactions. (c) 2022 Elsevier B.V. All rights reserved.en_US
dc.description.sponsorshipScience Committee of the Min-istry of Education and Science of the Republic of Kazakhstan [AP08856051]; Dicle University [FEN.21.005]en_US
dc.description.sponsorshipAcknowledgement This Research is funded by the Science Committee of the Min-istry of Education and Science of the Republic of Kazakhstan (Grant No. AP08856051) . Partial support from Dicle University (Project number: FEN.21.005) is gratefully acknowledged.en_US
dc.identifier.doi10.1016/j.molstruc.2022.133912
dc.identifier.issn0022-2860
dc.identifier.issn1872-8014
dc.identifier.scopus2-s2.0-85136032897
dc.identifier.scopusqualityQ1
dc.identifier.urihttps://doi.org/10.1016/j.molstruc.2022.133912
dc.identifier.urihttps://hdl.handle.net/11468/15877
dc.identifier.volume1270en_US
dc.identifier.wosWOS:000848422000001
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoenen_US
dc.publisherElsevieren_US
dc.relation.ispartofJournal of Molecular Structure
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectA-Hydroxy[1-(2-Ethoxyethyl)Piperidin-4-Yl]Phosphonateen_US
dc.subjectPd(Ii) And Pt(Ii) Complexesen_US
dc.subjectSuzuki-Miyaura Reactionen_US
dc.subjectDft Calculationsen_US
dc.titleSynthesis, and characterization of palladium(II) and platinum(II) complexes with ?-hydroxy[1-(2-ethoxyethyl) piperidin-4-yl]phosphonate and use of the palladium(II) complex as pre-catalyst in Suzuki-Miyaura cross-coupling reactionsen_US
dc.titleSynthesis, and characterization of palladium(II) and platinum(II) complexes with ?-hydroxy[1-(2-ethoxyethyl) piperidin-4-yl]phosphonate and use of the palladium(II) complex as pre-catalyst in Suzuki-Miyaura cross-coupling reactions
dc.typeArticleen_US

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