Temperature dependence of NMR T1 relaxation of dibenzo diaza 18-crown-6 ether derivative in solution

[ X ]

Tarih

2007

Dergi Başlığı

Dergi ISSN

Cilt Başlığı

Yayıncı

Asian Journal Of Chemistry

Erişim Hakkı

info:eu-repo/semantics/closedAccess

Özet

Spin-lattice relaxation times in one of dibenzo diaza 18-crown-6 ether derivative were measured vs. increasing temperature. The relaxation times (In T-1) were fitted vs. I/T over a temperature range of 313-277 K. A linear relationship with a negative slope was found for each peak. The present data suggest that In T, is nearly linearly proportional to I/T. The data also suggest that dipole-dipole interaction, modulated by whole molecular tumbling, is the source of relaxation.

Açıklama

Anahtar Kelimeler

Nmr, T-1, Relaxation, Supramolecular Chemistry, Crown Ethers

Kaynak

Asian Journal of Chemistry

WoS Q Değeri

Q4

Scopus Q Değeri

Q4

Cilt

19

Sayı

3

Künye