Temperature dependence of NMR T1 relaxation of dibenzo diaza 18-crown-6 ether derivative in solution
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Tarih
2007
Yazarlar
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Asian Journal Of Chemistry
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
Spin-lattice relaxation times in one of dibenzo diaza 18-crown-6 ether derivative were measured vs. increasing temperature. The relaxation times (In T-1) were fitted vs. I/T over a temperature range of 313-277 K. A linear relationship with a negative slope was found for each peak. The present data suggest that In T, is nearly linearly proportional to I/T. The data also suggest that dipole-dipole interaction, modulated by whole molecular tumbling, is the source of relaxation.
Açıklama
Anahtar Kelimeler
Nmr, T-1, Relaxation, Supramolecular Chemistry, Crown Ethers
Kaynak
Asian Journal of Chemistry
WoS Q Değeri
Q4
Scopus Q Değeri
Q4
Cilt
19
Sayı
3