Developments in transfer hydrogenations of aromatic ketones catalyzed by boron compounds

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dc.contributor.authorPasa, Salih
dc.contributor.authorGurler, Nedim
dc.contributor.authorTemel, Hamdi
dc.contributor.authorRafikova, Khadichakhan
dc.contributor.authorAydemir, Murat
dc.date.accessioned2024-04-24T16:24:25Z
dc.date.available2024-04-24T16:24:25Z
dc.date.issued2017
dc.departmentDicle Üniversitesien_US
dc.description.abstractBoron complexes BL1 and BL2 were prepared from O-donor ligands, 2,2'-(1E,1'E)-(ethane-1,2-diylbis(azan-1-yl-1-ylidene))bis(methane-1yl-1-ylidene)diphenol (L1) and 2,2'-(propane-1,3-diylbis(azan-1-yl-1ylidene)) bis(methane-1-yl-1-ylidene) diphenol (L2). The complexes were fully characterized by H-1 and C-13 NMR, LC-MS/MS, TGA/DTA, UV-Vis, elemental analysis, SEM, and FTIR. The transfer hydrogenation of acetophenone derivatives was investigated by the boron complexes in the presence of isoPrOH, as the hydrogen source, under basic condition with NaOH. The results showed that the boron complexes were promising catalytic precursors for transfer hydrogenation of aromatic ketones in 0.1 M isoPrOH solution (up to 99%). Both steric and electronic factors of this class of molecules had a significant impact on the catalytic properties. [GRAPHICS] .en_US
dc.description.sponsorshipTurkish Academy of Sciences; Dicle University [FEN.16.010, DUBAP FEN.15.021, FEN.15.022, DOAPK 05-FF-27, 14-EZF-14]en_US
dc.description.sponsorshipPartial supports of this work by Turkish Academy of Sciences and Dicle University (Project numbers: FEN.16.010 (NMR), DUBAP FEN.15.021, FEN.15.022, DOAPK 05-FF-27, and 14-EZF-14), and the analysis conducted by the Dicle University Science and Technology Research Center (DUBTAM) is gratefully acknowledged.en_US
dc.identifier.doi10.1080/00958972.2017.1300659
dc.identifier.endpage1367en_US
dc.identifier.issn0095-8972
dc.identifier.issn1029-0389
dc.identifier.issue8en_US
dc.identifier.scopus2-s2.0-85016048183
dc.identifier.scopusqualityQ3
dc.identifier.startpage1357en_US
dc.identifier.urihttps://doi.org/10.1080/00958972.2017.1300659
dc.identifier.urihttps://hdl.handle.net/11468/16706
dc.identifier.volume70en_US
dc.identifier.wosWOS:000398291400005
dc.identifier.wosqualityQ3
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoenen_US
dc.publisherTaylor & Francis Ltden_US
dc.relation.ispartofJournal of Coordination Chemistry
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectHomogeneous Catalysisen_US
dc.subjectBoron Complexesen_US
dc.subjectSpectroscopyen_US
dc.subjectAromatic Ketonesen_US
dc.subjectCatalysisen_US
dc.subjectTransfer Hydrogenationen_US
dc.titleDevelopments in transfer hydrogenations of aromatic ketones catalyzed by boron compoundsen_US
dc.titleDevelopments in transfer hydrogenations of aromatic ketones catalyzed by boron compounds
dc.typeArticleen_US

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