Removal of 17 beta-estradiol from aqueous systems with hydrophobic microspheres

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dc.authorid0000-0002-0761-6436en_US
dc.contributor.authorKireç, Osman
dc.contributor.authorAlacabey, İhsan
dc.contributor.authorErol, Kadir
dc.contributor.authorAlkan, Hüseyin
dc.date.accessioned2021-04-08T08:36:24Z
dc.date.available2021-04-08T08:36:24Z
dc.date.issued2021en_US
dc.departmentDicle Üniversitesi, Fen Bilimleri Enstitüsü, Kimya Ana Bilim Dalıen_US
dc.descriptionWOS:000626345100007
dc.description.abstractSub-microparticles have many applications in different fields today. In this study, it is aimed to develop hydrophobic microparticles as an alternative to existing methods and to determine the 17 beta-estradiol adsorption performance of this adsorbent to purify the 17 beta-estradiol hormone which is found as an endocrine disruptor in environmental waters with high capacity and low cost. In this study, L-phenylalanine containing Poly(HEMA-MAPA) microparticles were synthesized by microemulsion polymerization and used as adsorbent. Microparticles were characterized by Fourier transform infrared spectroscopy (FT-IR) and scanning electron microscope (SEM) methods. The size of the Poly(HEMA-MAPA) microparticles used was measured as 120-200 nm. Specific surface area and elemental analysis studies were also conducted. While the surface area of the particles was found to be a very high value of 1890 m(2)/g, the amount of incorporation of MAPA into the polymeric structure was calculated as 0.43 mmol/g. Adsorption studies were carried out in the batch system under different ambient conditions (17 beta-estradiol concentration, temperature, ionic intensity). The adsorption capacity of Poly(HEMA-MAPA) microparticles was calculated to be 98.4 mg/ g. Isotherm models for adsorption interaction were investigated deeply, and it was determined that the adsorption mechanism is suitable for Langmuir isotherm.en_US
dc.identifier.citationKireç, O., Alacabey, İ., Erol, K. ve Alkan, H. (2021). Removal of 17 beta-estradiol from aqueous systems with hydrophobic microspheres. Journal of Polymer Engineering, 41(3), 226-234.en_US
dc.identifier.doi10.1515/polyeng-2020-0150
dc.identifier.endpage234en_US
dc.identifier.issn0334-6447
dc.identifier.issn2191-0340
dc.identifier.issue3en_US
dc.identifier.scopus2-s2.0-85100996087
dc.identifier.scopusqualityQ3
dc.identifier.startpage226en_US
dc.identifier.urihttps://www.degruyter.com/document/doi/10.1515/polyeng-2020-0150/html
dc.identifier.urihttps://hdl.handle.net/11468/6609
dc.identifier.volume41en_US
dc.identifier.wosWOS:000626345100007
dc.identifier.wosqualityQ4
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.institutionauthorAlkan, Hüseyin
dc.institutionauthorKireç, Osman
dc.language.isoenen_US
dc.publisherWalter De Gruyter GMBHen_US
dc.relation.ispartofJournal of Polymer Engineering
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.subjectAdsorptionen_US
dc.subjectEstradiolen_US
dc.subjectHydrophobicen_US
dc.subjectl-phenylalanineen_US
dc.subjectMicroparticleen_US
dc.titleRemoval of 17 beta-estradiol from aqueous systems with hydrophobic microspheresen_US
dc.titleRemoval of 17 beta-estradiol from aqueous systems with hydrophobic microspheres
dc.typeArticleen_US

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