Synthesis and spectral characterization of macrocyclic NiII complexes derived from various diamines, NiII perchlorate and 1,4-bis(2-carboxyaldehydephenoxy)butane

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dc.contributor.authorIlhan, Salih
dc.contributor.authorTemel, Hamdi
dc.contributor.authorKilic, Ahmet
dc.contributor.authorTas, Esref
dc.date.accessioned2024-04-24T16:02:22Z
dc.date.available2024-04-24T16:02:22Z
dc.date.issued2007
dc.departmentDicle Üniversitesien_US
dc.description.abstractSix new macrocyclic complexes were synthesized by reaction of 1,4-bis(2-carboxyaldehyde phenoxy)butane with various diamines. Then, their nickel(II) perchlorate complexes were synthesized by the template effect by reaction of 1,4-bis(2-carboxyaldehyde phenoxy)butane, Ni(ClO4)(2) center dot 6H(2)O and various diamines. The metal-to-ligand ratio of Ni-II metal complexes was found to be 1:1. The compounds are coordinated to the central metal as tetradentate O2N2 ligands The Ni-II complexes are proposed to exhibit tetrahedral geometry. Ni-II metal complexes are 1:2 electrolytes as shown by their molar conductivities (Lambda(M)) in DMF (dimethyl formamide) at 10(-3) M. The structure of Ni-II metal complexes is proposed from elemental analysis, f.t.-i.r., u.v.-vis., magnetic susceptibility measurements, molar conductivity measurements and mass spectra.en_US
dc.identifier.doi10.1007/s11243-007-0260-0
dc.identifier.endpage1017en_US
dc.identifier.issn0340-4285
dc.identifier.issn1572-901X
dc.identifier.issue8en_US
dc.identifier.scopus2-s2.0-34848915430
dc.identifier.scopusqualityQ2
dc.identifier.startpage1012en_US
dc.identifier.urihttps://doi.org/10.1007/s11243-007-0260-0
dc.identifier.urihttps://hdl.handle.net/11468/14766
dc.identifier.volume32en_US
dc.identifier.wosWOS:000249666100002
dc.identifier.wosqualityQ3
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoenen_US
dc.publisherSpringeren_US
dc.relation.ispartofTransition Metal Chemistry
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subject[No Keyword]en_US
dc.titleSynthesis and spectral characterization of macrocyclic NiII complexes derived from various diamines, NiII perchlorate and 1,4-bis(2-carboxyaldehydephenoxy)butaneen_US
dc.titleSynthesis and spectral characterization of macrocyclic NiII complexes derived from various diamines, NiII perchlorate and 1,4-bis(2-carboxyaldehydephenoxy)butane
dc.typeArticleen_US

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