The solvent extraction of boron with synthesized aliphatic 1,3-diols

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dc.contributor.authorKarakaplan, M
dc.contributor.authorTural, S
dc.contributor.authorTural, B
dc.contributor.authorTurgut, Y
dc.contributor.authorHosgören, H
dc.date.accessioned2024-04-24T17:07:56Z
dc.date.available2024-04-24T17:07:56Z
dc.date.issued2004
dc.departmentDicle Üniversitesien_US
dc.description.abstractA variety of aliphatic 1,3-diols (4a-c, 5a-c, 6a-c) was synthesized from beta-hydroxy carbonyl compounds (1-3) for potential use in the solvent extraction of boron. Primary-secondary and primary-tertiary alcohol structures of 1,3-diols substituted with isopropyl, isobutyl, and isopentyl groups have been demonstrated to be very efficient for the solvent extraction of boric acid from aqueous solutions. The extraction ability of 2,2,5-trimethyl-1,3-hexanediol (5b) was investigated as a function of 5b concentration, solution pH, solvent properties, and stripping conditions. Extraction efficiency increased with increasing concentration of 5b, and the best extraction of boron (96.8%) was found to be at an equilibrium pH of 2 with 0.5 M of 5b. Chloroform, toluene, chlorobenzene, 2-octanol, and n-amyl alcohol were found to be suitable solvents for the solvent extraction of boron. The boron complex can be recovered from the organic phase by treatment with an aqueous solution of sodium hydroxide. The highest ratio (96.7%) of boron was recovered by 0.1 M of sodium hydroxide solution.en_US
dc.identifier.doi10.1081/SEI-200037400
dc.identifier.endpage911en_US
dc.identifier.issn0736-6299
dc.identifier.issn1532-2262
dc.identifier.issue6en_US
dc.identifier.scopus2-s2.0-10244257603
dc.identifier.scopusqualityQ2
dc.identifier.startpage897en_US
dc.identifier.urihttps://doi.org/10.1081/SEI-200037400
dc.identifier.urihttps://hdl.handle.net/11468/17105
dc.identifier.volume22en_US
dc.identifier.wosWOS:000225245200001
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoenen_US
dc.publisherTaylor & Francis Incen_US
dc.relation.ispartofSolvent Extraction and Ion Exchange
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subject1,3-Diolsen_US
dc.subjectBoron Determinationen_US
dc.subjectSolvent Extraction Of Boronen_US
dc.subjectStripping Of Boronen_US
dc.subjectBeta-Hydroxyl Carbonyl Compoundsen_US
dc.titleThe solvent extraction of boron with synthesized aliphatic 1,3-diolsen_US
dc.titleThe solvent extraction of boron with synthesized aliphatic 1,3-diols
dc.typeArticleen_US

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