Synthesis, spectroscopic and electrochemical studies of novel transition metal complexes with quadridentate Schiff base

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dc.contributor.authorTemel, Hamdi
dc.contributor.authorİlhan, Salih
dc.contributor.authorAslanoğlu, Mehmet
dc.contributor.authorKılıç, Ahmet
dc.contributor.authorTaş, Eşref
dc.date.accessioned2024-04-24T15:59:25Z
dc.date.available2024-04-24T15:59:25Z
dc.date.issued2006
dc.departmentDicle Üniversitesi, Eczacılık Fakültesi, Eczacılık Meslek Bilimleri Bölümüen_US
dc.description.abstractA novel quadridentate, N2O2 type Schiff base, synthesized from 1,4-bis-(o-aminophenoxy)butane and 2-hydroxynaphthalin-1-carbaldehyde, forms stable complexes with transition metal ions such as Co(II), Cu(II) and Ni(II) in DMF. Microanalytical data, elemental analysis, magnetic measurements, UV-visible and IR-spectra as well as conductance measurements were used to confirm the structures: Electrochemical measurements show that metal complexes undergo quasi-reversible one-electron redox processes. The voltammetric results also revealed that the CuL complex has the highest electron transfer rate indicating that both the Cu(II) and Cu(I) forms appear in a similar planar configuration, so the electron transfer does not require larger reorganization of the complex.en_US
dc.identifier.citationTemel, H., İlhan, S., Aslanoğlu, M., Kılıç, A. ve Taş, E. (2006). Synthesis, spectroscopic and electrochemical studies of novel transition metal complexes with quadridentate Schiff base. Journal of The Chinese Chemical Society, 53(5), 1027-1031.
dc.identifier.doi10.1002/jccs.200600136
dc.identifier.endpage1031en_US
dc.identifier.issn0009-4536
dc.identifier.issn2192-6549
dc.identifier.issue5en_US
dc.identifier.scopus2-s2.0-34548347161
dc.identifier.scopusqualityQ2
dc.identifier.startpage1027en_US
dc.identifier.urihttps://doi.org/10.1002/jccs.200600136
dc.identifier.urihttps://hdl.handle.net/11468/14056
dc.identifier.urihttps://onlinelibrary.wiley.com/doi/10.1002/jccs.200600136
dc.identifier.volume53en_US
dc.identifier.wosWOS:000241714800005
dc.identifier.wosqualityQ3
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.institutionauthorTemel, Hamdi
dc.institutionauthorİlhan, Salih
dc.language.isoenen_US
dc.publisherWiley-V C H Verlag Gmbhen_US
dc.relation.ispartofJournal of The Chinese Chemical Society
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectSchiff baseen_US
dc.subjectCo(Ii)en_US
dc.subjectCu(Ii) And Ni(Ii) complexesen_US
dc.subjectSpectroscopic studiesen_US
dc.subjectRedox propertiesen_US
dc.titleSynthesis, spectroscopic and electrochemical studies of novel transition metal complexes with quadridentate Schiff baseen_US
dc.titleSynthesis, spectroscopic and electrochemical studies of novel transition metal complexes with quadridentate Schiff base
dc.typeArticleen_US

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