Spectroscopic and conductance studies of new transition metal complexes with a Schiff base derived from 4-methoxybenzaldehyde and 1,2-bis(p-aminophenoxy)ethane
dc.contributor.author | Çakir, Ü | |
dc.contributor.author | Temel, H | |
dc.contributor.author | Ilhan, S | |
dc.contributor.author | Ugras, HI | |
dc.date.accessioned | 2024-04-24T17:07:57Z | |
dc.date.available | 2024-04-24T17:07:57Z | |
dc.date.issued | 2003 | |
dc.department | Dicle Üniversitesi | en_US |
dc.description.abstract | Four new metal complexes of Cu(II), Ni(II), Zn(II) and Co(III) with Schiff base derived from 4-methoxybenzaldehyde and 1,2-bis(p-aminophenoxy)ethane have been prepared and characterized by magnetic susceptibility, conductance measurements, elemental analyses, UV-Vis, H-1 NMR and IR spectra studies. The magnetic and spectroscopic data indicate an octahedral geometry for the six-coordinate complexes. The ligand was used for complexation studies. Stability constants were measured by means of a conductometric method. Furthermore, the stability constants for complexation between ZnCl2, Cu(NO3)(2) and AgNO3 salts and ligand (L) in 80% dioxane-water and pure methanol were determined from conductance measurements. In 80% dioxane-water, the stability constants (log Ke) increase inversely with the crystal radii in the order Ag(I) < Zn(II) < Cu(II). | en_US |
dc.identifier.doi | 10.1081/SL-120026609 | |
dc.identifier.endpage | 440 | en_US |
dc.identifier.issn | 0038-7010 | |
dc.identifier.issn | 1532-2289 | |
dc.identifier.issue | 5-6 | en_US |
dc.identifier.scopus | 2-s2.0-0346750672 | |
dc.identifier.scopusquality | Q3 | |
dc.identifier.startpage | 429 | en_US |
dc.identifier.uri | https://doi.org/10.1081/SL-120026609 | |
dc.identifier.uri | https://hdl.handle.net/11468/17113 | |
dc.identifier.volume | 36 | en_US |
dc.identifier.wos | WOS:000187352600003 | |
dc.identifier.wosquality | Q4 | |
dc.indekslendigikaynak | Web of Science | |
dc.indekslendigikaynak | Scopus | |
dc.language.iso | en | en_US |
dc.publisher | Taylor & Francis Inc | en_US |
dc.relation.ispartof | Spectroscopy Letters | |
dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
dc.rights | info:eu-repo/semantics/closedAccess | en_US |
dc.subject | 1,2-Bis(P-Aminophenoky)Ethane | en_US |
dc.subject | 4-Methoxybenzaldehyde | en_US |
dc.subject | Schiff Base Complexes | en_US |
dc.subject | Spectra Studies And Stability Constants | en_US |
dc.title | Spectroscopic and conductance studies of new transition metal complexes with a Schiff base derived from 4-methoxybenzaldehyde and 1,2-bis(p-aminophenoxy)ethane | en_US |
dc.title | Spectroscopic and conductance studies of new transition metal complexes with a Schiff base derived from 4-methoxybenzaldehyde and 1,2-bis(p-aminophenoxy)ethane | |
dc.type | Article | en_US |