Boron containing chiral Schiff bases: Synthesis and catalytic activity in asymmetric transfer hydrogenation (ATH) of ketones

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dc.contributor.authorPasa, Salih
dc.contributor.authorArslan, Nevin
dc.contributor.authorMeric, Nermin
dc.contributor.authorKayan, Cezmi
dc.contributor.authorBingul, Murat
dc.contributor.authorDurap, Feyyaz
dc.contributor.authorAydemir, Murat
dc.date.accessioned2024-04-24T16:15:37Z
dc.date.available2024-04-24T16:15:37Z
dc.date.issued2020
dc.departmentDicle Üniversitesien_US
dc.description.abstractAsymmetric Transfer Hydrogenation (ATH) has been an attractive way for the reduction of ketones to chiral alcohols. A great number of novel and valuable synthetic pathways have been achived by the combination usage of organometallic and coordination chemistry for the production of important class of compounds and particularly optically active molecules. For this aim, four boron containing Schiff bases were synthesized by the reaction of 4-formylphenylboronic acid with chiral amines. The boron containing structures have been found as stable compounds due to the presence of covalent B-O bonds and thus could be handled in laboratory environment. They were characterized by H-1 NMR and FT-IR spectroscopy and elemental analysis and they were used as catalyst in the transfer hydrogenation of ketones to the related alcohol derivatives with high conversions (up to 99%) and low enantioselectivities (up to 22% ee). (C) 2019 Elsevier B.V. All rights reserved.en_US
dc.description.sponsorshipResearch Fund of Afyon Kocatepe University [18.KARIYER.89]en_US
dc.description.sponsorshipI would like to thank to the Research Fund of Afyon Kocatepe University that supported my study with the grant number 18.KARIYER.89. And I alsowant to expressmy special thanks to Prof. Dr. Huseyin Enginar and Prof. Dr. Ibrahim Erol for their able guidance and support with laboratory facilities.en_US
dc.identifier.doi10.1016/j.molstruc.2019.127064
dc.identifier.issn0022-2860
dc.identifier.issn1872-8014
dc.identifier.scopus2-s2.0-85072252919
dc.identifier.scopusqualityQ1
dc.identifier.urihttps://doi.org/10.1016/j.molstruc.2019.127064
dc.identifier.urihttps://hdl.handle.net/11468/15869
dc.identifier.volume1200en_US
dc.identifier.wosWOS:000496810900003
dc.identifier.wosqualityQ3
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoenen_US
dc.publisherElsevieren_US
dc.relation.ispartofJournal of Molecular Structure
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectHomogeneous Catalysisen_US
dc.subjectBoron Compounden_US
dc.subjectChiral Schiff Baseen_US
dc.subjectAsymmetric Transfer Hydrogenationen_US
dc.subjectAromatic Ketoneen_US
dc.titleBoron containing chiral Schiff bases: Synthesis and catalytic activity in asymmetric transfer hydrogenation (ATH) of ketonesen_US
dc.titleBoron containing chiral Schiff bases: Synthesis and catalytic activity in asymmetric transfer hydrogenation (ATH) of ketones
dc.typeArticleen_US

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