Enantioselective complexation of chiral lariat crown ethers and chiral primary alkylammonium perchlorates

Basit Öğe Kaydı
dc.contributor.authorKoylu, M. Zafer
dc.contributor.authorAral, Tarik
dc.contributor.authorKarakaplan, Mehmet
dc.contributor.authorKocakaya, Safak Ozhan
dc.contributor.authorHosgoren, Halil
dc.date.accessioned2024-04-24T17:21:03Z
dc.date.available2024-04-24T17:21:03Z
dc.date.issued2011
dc.departmentDicle Üniversitesien_US
dc.description.abstractIn order to investigate the enantiomeric recognition abilities toward 2 chiral alkylammonium perchlorates (AmI, AmII) by H-1-NMR titration method in CDCl3, 4 chiral lariat ethers 8-11 with a (p-methoxyphenoxy) methyl flexible side arm were used. The most effective enantiomeric recognition was obtained by LCEs 9 and 11 toward AmII, by K-R/K-S 6.58 and K-S/K-R 6.63, respectively. The effect of macroring size, subunit of macroring, and side arm appeared to have strong influence on the binding ability of these alkylammonium ions.en_US
dc.description.sponsorshipResearch Project Council of Dicle University (DUAPK) [DUAPK-09-FF-13]en_US
dc.description.sponsorshipThis research was supported by the Research Project Council of Dicle University (DUAPK) (Project No. DUAPK-09-FF-13).en_US
dc.identifier.doi10.3906/kim-1008-844
dc.identifier.endpage179en_US
dc.identifier.issn1300-0527
dc.identifier.issue2en_US
dc.identifier.startpage171en_US
dc.identifier.trdizinid114391
dc.identifier.urihttps://doi.org/10.3906/kim-1008-844
dc.identifier.urihttps://search.trdizin.gov.tr/yayin/detay/114391
dc.identifier.urihttps://hdl.handle.net/11468/19353
dc.identifier.volume35en_US
dc.identifier.wosWOS:000288096600001
dc.identifier.wosqualityQ3
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakTR-Dizin
dc.language.isoenen_US
dc.publisherTubitak Scientific & Technological Research Council Turkeyen_US
dc.relation.ispartofTurkish Journal of Chemistry
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.subjectChiral Lariat Crown Ethersen_US
dc.subjectEnantioselectivityen_US
dc.subjectComplexation Propertiesen_US
dc.subjectMolecular Recognitionen_US
dc.subjectNmr Titrationen_US
dc.titleEnantioselective complexation of chiral lariat crown ethers and chiral primary alkylammonium perchloratesen_US
dc.titleEnantioselective complexation of chiral lariat crown ethers and chiral primary alkylammonium perchlorates
dc.typeArticleen_US

Dosyalar

Koleksiyon

WoS İndeksli Yayınlar Koleksiyonu
TR-Dizin İndeksli Yayınlar Koleksiyonu