Microwave-assisted synthesis of novel amide based chiral tripodal receptors for recognition of cation and anion sensors

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dc.contributor.authorAzizoglu, Sevil S.
dc.contributor.authorKaplan, Seref
dc.contributor.authorOzturk, Gulsen
dc.contributor.authorTurgut, Yilmaz
dc.contributor.authorTogrul, Mahmut
dc.date.accessioned2024-04-24T17:24:09Z
dc.date.available2024-04-24T17:24:09Z
dc.date.issued2016
dc.departmentDicle Üniversitesien_US
dc.description.abstractFive novel amide based chiral tripodal receptors were synthesized under microwave irradiation by reacting nitrilotriacetic acid with chiral amino alcohols in a solvent-free medium with high yields (>= 90%). The recognition affinities of these tripodal receptors were investigated towards anions and chiral organic ammonium cations using H-1 NMR titration method. The results show that receptor 1 displays more affinity against anions compared with other receptors and the tripodal receptor 4 demonstrated a significant enantiomeric selectivity towards the (R)-naphthylethylammonium perchlorate (ERF 54%).en_US
dc.description.sponsorshipScientific and Technological Research Council of Turkey (TUBITAK) [109 T 787]en_US
dc.description.sponsorshipWe would like to thank The Scientific and Technological Research Council of Turkey (TUBITAK) for financially supporting this research (Project No: 109 T 787). We are grateful to Dr. Necmettin Pirincioglu (Dicle University) for their invaluable contribution.en_US
dc.identifier.doi10.3998/ark.5550190.p009.434
dc.identifier.endpage58en_US
dc.identifier.issn1551-7004
dc.identifier.issn1551-7012
dc.identifier.scopus2-s2.0-84973169019en_US
dc.identifier.scopusqualityQ4en_US
dc.identifier.startpage44en_US
dc.identifier.urihttps://doi.org/10.3998/ark.5550190.p009.434
dc.identifier.urihttps://hdl.handle.net/11468/19454
dc.identifier.wosWOS:000377613000004en_US
dc.identifier.wosqualityQ3en_US
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoenen_US
dc.publisherArkat Usa Incen_US
dc.relation.ispartofArkivocen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.subjectTripodal Receptoren_US
dc.subjectCation Sensoren_US
dc.subjectAnion Sensoren_US
dc.subjectMicrowave And Nmr Titrationen_US
dc.titleMicrowave-assisted synthesis of novel amide based chiral tripodal receptors for recognition of cation and anion sensorsen_US
dc.typeArticleen_US

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