Green synthesis of Co-based nanoparticles from Rheum ribes shell extract and determination of the effect of their activity on sodium borohydride hydrolysis

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dc.authorid0000-0002-2915-202Xen_US
dc.authorid0000-0003-1451-1023en_US
dc.authorid0000-0002-3068-8657en_US
dc.contributor.authorBaytar, Orhan
dc.contributor.authorŞahin, Ömer
dc.contributor.authorGenli, Nasrettin
dc.contributor.authorEkinci, Arzu
dc.date.accessioned2024-08-16T08:38:31Z
dc.date.available2024-08-16T08:38:31Z
dc.date.issued2024en_US
dc.departmentDicle Üniversitesi, Diyarbakır Teknik Bilimler Meslek Yüksekokulu, Kimya ve Kimyasal İşleme Teknolojileri Bölümüen_US
dc.description.abstractAbstract This study investigated the effect of Co(0) and Co-B NP catalysts synthesized by the green synthesis method using Rheum ribes shell extract on the NaBH4 hydrolysis process for the first time, and determined the role of the green synthesis method in the catalyst activity. The investigation of the structure and surface morphology of the catalysts was evaluated using XRD, SEM–EDX, TEM, FTIR, and XPS analyses. The effect of catalysts on NaBH4 was examined at different catalyst amounts, different NaBH4/NaOH concentrations, and different temperature values. The Co(0) and CoB NPs catalysts achieved the greatest HGR values at a solution temperature of 30 °C, with values of 7326 mLmin−1g−1cat and 12,524 mLmin−1g−1cat, respectively. The calculated activation energies for Co(0) and Co-B NPs catalysts are 37.68 kJmol−1 and 21.28 kJmol−1, respectively. The green synthesis method synthesized Co(0) and Co-B catalysts significantly increased hydrogen production activity compared to the cobalt-based catalysts synthesized by other methods.en_US
dc.identifier.citationBaytar, O., Şahin, Ö., Genli, N. ve Ekinci, A. (2024). Green synthesis of Co-based nanoparticles from Rheum ribes shell extract and determination of the effect of their activity on sodium borohydride hydrolysis. Ionics, 1-15.en_US
dc.identifier.endpage15en_US
dc.identifier.issn0947-7047
dc.identifier.scopus2-s2.0-85197452911
dc.identifier.scopusqualityQ1
dc.identifier.startpage1en_US
dc.identifier.urihttps://link.springer.com/article/10.1007/s11581-024-05654-7
dc.identifier.urihttps://hdl.handle.net/11468/28752
dc.identifier.wosWOS:001260523100001
dc.identifier.wosqualityN/A
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.institutionauthorGenli, Nasrettin
dc.language.isoenen_US
dc.publisherSpringer Science and Business Media Deutschland GmbHen_US
dc.relation.ispartofIonics
dc.relation.isversionof10.1007/s11581-024-05654-7en_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectCo-based catalystsen_US
dc.subjectExtracten_US
dc.subjectGreen synthesisen_US
dc.subjectHydrolysisen_US
dc.subjectNanoparticlesen_US
dc.titleGreen synthesis of Co-based nanoparticles from Rheum ribes shell extract and determination of the effect of their activity on sodium borohydride hydrolysisen_US
dc.titleGreen synthesis of Co-based nanoparticles from Rheum ribes shell extract and determination of the effect of their activity on sodium borohydride hydrolysis
dc.typeArticleen_US

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