Application of phthalocyanine complexes of Cu(II), Co(II), Ni(II), and Zn(II) as catalysts in the transfer hydrogenation of acetophenone and its derivatives

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dc.authorid0000-0001-9929-021Xen_US
dc.authorid0000-0003-1010-9563en_US
dc.authorid0000-0002-5234-0782en_US
dc.contributor.authorNamlı, Mesut
dc.contributor.authorIşık, Uğur
dc.contributor.authorKantar, Cihan
dc.contributor.authorAydemir, Murat
dc.date.accessioned2024-06-24T08:57:26Z
dc.date.available2024-06-24T08:57:26Z
dc.date.issued2024en_US
dc.departmentDicle Üniversitesi, Fen Fakültesi, Kimya Bölümüen_US
dc.description.abstractIn this study, tetra substituted metallophthalocyanines (M: Ni, Zn, Co, and Cu) containing imine and azo groups were synthesized using microwave irradiation. The structures of all complexes have been totally characterized via 1HNMR, 13CNMR, TGA/DTA, LC-MS/MS, elemental analysis, UV–Vis, FT-IR spectroscopy. The comparison of the catalytic features of phthalocyanine based on metals is also discussed briefly. These phthalocyanine-complexes were also used in the transfer hydrogenation (TH) of acetophenone derivatives in the existence of KOH, utilizing isoPrOH as a hydrogen source. Acetophenone compounds determined a TH of up to 99 % conversion. Copper phthalocyanines were first used as catalysts in transfer hydrogenation reactions. The Cu(II) complexes showed higher catalytic activity, converting up to 97 % at 1.0 mol% catalyst loading. Furthermore, we have discovered that the catalytic characteristics of this class of molecules are significantly influenced by both steric and electronic variables.en_US
dc.identifier.citationNamlı, M., Işık, U., Kantar, C. ve Aydemir, M. (2024). Application of phthalocyanine complexes of Cu(II), Co(II), Ni(II), and Zn(II) as catalysts in the transfer hydrogenation of acetophenone and its derivatives. Journal of Molecular Structure, 1312, 1-10.en_US
dc.identifier.endpage10en_US
dc.identifier.issn0022-2860
dc.identifier.scopus2-s2.0-85192685174
dc.identifier.scopusqualityQ1
dc.identifier.startpage1en_US
dc.identifier.urihttps://www.sciencedirect.com/science/article/pii/S0022286024009670?via%3Dihub
dc.identifier.urihttps://hdl.handle.net/11468/28675
dc.identifier.volume1312en_US
dc.identifier.wosWOS:001240570300001
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.institutionauthorAydemir, Murat
dc.language.isoenen_US
dc.publisherElsevier Ltd.en_US
dc.relation.ispartofJournal of Molecular Structure
dc.relation.isversionof10.1016/j.molstruc.2024.138447en_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectAromatic ketonesen_US
dc.subjectCatalysisen_US
dc.subjectCopperen_US
dc.subjectPhthalocyanineen_US
dc.subjectTransfer hydrogenationen_US
dc.titleApplication of phthalocyanine complexes of Cu(II), Co(II), Ni(II), and Zn(II) as catalysts in the transfer hydrogenation of acetophenone and its derivativesen_US
dc.titleApplication of phthalocyanine complexes of Cu(II), Co(II), Ni(II), and Zn(II) as catalysts in the transfer hydrogenation of acetophenone and its derivatives
dc.typeArticleen_US

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