Synthesis and spectroscopic characterization of a new macrocyclic Schiff base formed by the reaction of 1,5-bis(2-formylphenyl)pentane and 2,6-diaminopyridine, and a study of its metal complexes

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dc.contributor.authorIlhan, Salih
dc.contributor.authorTemel, Hamdi
dc.date.accessioned2024-04-24T16:24:25Z
dc.date.available2024-04-24T16:24:25Z
dc.date.issued2009
dc.departmentDicle Üniversitesien_US
dc.description.abstractA new dialdehyde 1,5-bis(2-formylphenyl)pentane was synthesized from 1,5-dibromopentane with salicylaldehyde and K2CO3; macrocyclic ligand was synthesized by reaction of 2,6-diaminopyridine and 1,5-bis(2-formylphenyl) pentane. Cu(II), Ni(II), Pb(II), Zn(II), Cd(II) and La(III) complexes were synthesized by reaction of the ligand and Cu(ClO4)(2) center dot 6H(2)O, Ni(ClO4)(2) center dot 6H(2)O, Pb(ClO4)(2) center dot 6H(2)O, Zn(ClO4)(2) center dot 6H(2)O, Cd(ClO4)(2) center dot 6H(2)O and La(ClO4)(3) center dot 6H(2)O, respectively. The ligand and its metal complexes have been characterized by elemental analysis, IR, H-1 and C-13 NMR, UV-Vis spectra, magnetic susceptibility, conductivity measurements and mass spectra. All complexes are diamagnetic and Cu(II) complex is binuclear.en_US
dc.identifier.doi10.1080/00958970802251765
dc.identifier.endpage464en_US
dc.identifier.issn0095-8972
dc.identifier.issn1029-0389
dc.identifier.issue3en_US
dc.identifier.scopus2-s2.0-58149117568
dc.identifier.scopusqualityQ3
dc.identifier.startpage456en_US
dc.identifier.urihttps://doi.org/10.1080/00958970802251765
dc.identifier.urihttps://hdl.handle.net/11468/16702
dc.identifier.volume62en_US
dc.identifier.wosWOS:000261921800012
dc.identifier.wosqualityQ3
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoenen_US
dc.publisherTaylor & Francis Ltden_US
dc.relation.ispartofJournal of Coordination Chemistry
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subject1,5-Bis(2-Formylphenyl)Pentaneen_US
dc.subject2,6-Diaminopyridineen_US
dc.subjectMacrocyclic Schiff Baseen_US
dc.subjectMacrocyclic Schiff-Base Complexesen_US
dc.titleSynthesis and spectroscopic characterization of a new macrocyclic Schiff base formed by the reaction of 1,5-bis(2-formylphenyl)pentane and 2,6-diaminopyridine, and a study of its metal complexesen_US
dc.titleSynthesis and spectroscopic characterization of a new macrocyclic Schiff base formed by the reaction of 1,5-bis(2-formylphenyl)pentane and 2,6-diaminopyridine, and a study of its metal complexes
dc.typeArticleen_US

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