Synthesis and structural characterization of a novel seven-coordinate cobalt(II) complex: 2,9-Bis(ethanolamine)-1,10-phenanthrolinechlorocobalt(II) chloride
dc.contributor.author | Baysal, Akin | |
dc.contributor.author | Aydemir, Murat | |
dc.contributor.author | Durap, Feyyaz | |
dc.contributor.author | Ozkar, Saim | |
dc.contributor.author | Yildirim, Leyla Tatar | |
dc.date.accessioned | 2024-04-24T16:14:52Z | |
dc.date.available | 2024-04-24T16:14:52Z | |
dc.date.issued | 2011 | |
dc.department | Dicle Üniversitesi | en_US |
dc.description.abstract | Condensation reaction of 2,9-dicarboxaldehyde-1,10-phenanthroline with 2-aminoethanol followed by NaBH4 reduction yielded the polydentate Schiff base ligand 2,9-bis(ethanolamine)-1,10-phenanthroline in its reduced form. This ligand was characterized by elemental analysis, LC-MS, IR, UV-Vis and NMR spectroscopy. Reaction of the reduced Schiff base ligand with aqueous solution of cobalt(II) chloride affords 2,9-bis(ethanolamine)-1,10-phenanthrolinechlorocobalt(II) chloride in high yield. Single crystals of the cobalt(II) complex were obtained from the crystallization in ethanol and its structure was elucidated by X-ray structural analysis. The cobalt(II) complex ion was found to be seven-coordinated in a pentagonal bipyramidal geometry, whereby cobalt(II) ion is surrounded by the six donor atoms in the ligand molecule and a chloride ion. (C) 2011 Elsevier B. V. All rights reserved. | en_US |
dc.description.sponsorship | Academy of Sciences and Hacettepe University Scientific Research Department | en_US |
dc.description.sponsorship | Partial support from Turkish Academy of Sciences and Hacettepe University Scientific Research Department is gratefully acknowledged. | en_US |
dc.identifier.doi | 10.1016/j.ica.2011.03.050 | |
dc.identifier.endpage | 110 | en_US |
dc.identifier.issn | 0020-1693 | |
dc.identifier.issn | 1873-3255 | |
dc.identifier.issue | 1 | en_US |
dc.identifier.scopus | 2-s2.0-79955814440 | |
dc.identifier.scopusquality | Q2 | |
dc.identifier.startpage | 107 | en_US |
dc.identifier.uri | https://doi.org/10.1016/j.ica.2011.03.050 | |
dc.identifier.uri | https://hdl.handle.net/11468/15454 | |
dc.identifier.volume | 371 | en_US |
dc.identifier.wos | WOS:000290392100017 | |
dc.identifier.wosquality | Q3 | |
dc.indekslendigikaynak | Web of Science | |
dc.indekslendigikaynak | Scopus | |
dc.language.iso | en | en_US |
dc.publisher | Elsevier Science Sa | en_US |
dc.relation.ispartof | Inorganica Chimica Acta | |
dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
dc.rights | info:eu-repo/semantics/closedAccess | en_US |
dc.subject | 1,10-Phenanthroline | en_US |
dc.subject | Schiff Base | en_US |
dc.subject | Cobalt | en_US |
dc.subject | Seven-Coordinate | en_US |
dc.subject | X-Ray | en_US |
dc.title | Synthesis and structural characterization of a novel seven-coordinate cobalt(II) complex: 2,9-Bis(ethanolamine)-1,10-phenanthrolinechlorocobalt(II) chloride | en_US |
dc.title | Synthesis and structural characterization of a novel seven-coordinate cobalt(II) complex: 2,9-Bis(ethanolamine)-1,10-phenanthrolinechlorocobalt(II) chloride | |
dc.type | Article | en_US |