Synthesis and structural characterization of a novel seven-coordinate cobalt(II) complex: 2,9-Bis(ethanolamine)-1,10-phenanthrolinechlorocobalt(II) chloride

dc.contributor.authorBaysal, Akin
dc.contributor.authorAydemir, Murat
dc.contributor.authorDurap, Feyyaz
dc.contributor.authorOzkar, Saim
dc.contributor.authorYildirim, Leyla Tatar
dc.date.accessioned2024-04-24T16:14:52Z
dc.date.available2024-04-24T16:14:52Z
dc.date.issued2011
dc.departmentDicle Üniversitesien_US
dc.description.abstractCondensation reaction of 2,9-dicarboxaldehyde-1,10-phenanthroline with 2-aminoethanol followed by NaBH4 reduction yielded the polydentate Schiff base ligand 2,9-bis(ethanolamine)-1,10-phenanthroline in its reduced form. This ligand was characterized by elemental analysis, LC-MS, IR, UV-Vis and NMR spectroscopy. Reaction of the reduced Schiff base ligand with aqueous solution of cobalt(II) chloride affords 2,9-bis(ethanolamine)-1,10-phenanthrolinechlorocobalt(II) chloride in high yield. Single crystals of the cobalt(II) complex were obtained from the crystallization in ethanol and its structure was elucidated by X-ray structural analysis. The cobalt(II) complex ion was found to be seven-coordinated in a pentagonal bipyramidal geometry, whereby cobalt(II) ion is surrounded by the six donor atoms in the ligand molecule and a chloride ion. (C) 2011 Elsevier B. V. All rights reserved.en_US
dc.description.sponsorshipAcademy of Sciences and Hacettepe University Scientific Research Departmenten_US
dc.description.sponsorshipPartial support from Turkish Academy of Sciences and Hacettepe University Scientific Research Department is gratefully acknowledged.en_US
dc.identifier.doi10.1016/j.ica.2011.03.050
dc.identifier.endpage110en_US
dc.identifier.issn0020-1693
dc.identifier.issn1873-3255
dc.identifier.issue1en_US
dc.identifier.scopus2-s2.0-79955814440
dc.identifier.scopusqualityQ2
dc.identifier.startpage107en_US
dc.identifier.urihttps://doi.org/10.1016/j.ica.2011.03.050
dc.identifier.urihttps://hdl.handle.net/11468/15454
dc.identifier.volume371en_US
dc.identifier.wosWOS:000290392100017
dc.identifier.wosqualityQ3
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoenen_US
dc.publisherElsevier Science Saen_US
dc.relation.ispartofInorganica Chimica Acta
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subject1,10-Phenanthrolineen_US
dc.subjectSchiff Baseen_US
dc.subjectCobalten_US
dc.subjectSeven-Coordinateen_US
dc.subjectX-Rayen_US
dc.titleSynthesis and structural characterization of a novel seven-coordinate cobalt(II) complex: 2,9-Bis(ethanolamine)-1,10-phenanthrolinechlorocobalt(II) chlorideen_US
dc.titleSynthesis and structural characterization of a novel seven-coordinate cobalt(II) complex: 2,9-Bis(ethanolamine)-1,10-phenanthrolinechlorocobalt(II) chloride
dc.typeArticleen_US

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