Effect of 1,3-diol structure on the distribution of boron between CHCl3 and aqueous phase
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Tarih
2003
Yazarlar
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Marcel Dekker Inc
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
The various new aliphatic 1,3-diols, containing primary, secondary, tertiary, and mixed of these groups, were synthesized and used for the solvent extraction of boron. Diols (8a, 8b, 9, 10a, 10b, 11, 12a, 12b, 13) were prepared from (beta-hydroxy carbonyl compounds 1-7. The fixed standard solution of boric acid of 1.00x10(-2) M was extracted with 0.1 M and 0.5 M diols at equilibrium pH of 2 and at constant ionic strength (I=0.5). The best extracting reagent was found to be 11, which is a primary-tertiary class of -OH groups and methyl groups as a substituent on the second carbon of 1,3-diol.
Açıklama
Anahtar Kelimeler
[No Keyword]
Kaynak
Separation Science and Technology
WoS Q Değeri
Q2
Scopus Q Değeri
Q2
Cilt
38
Sayı
8
