Bis[?2-2,2?-dimethyl-N,N?-bis(2-oxido-benzyl)propane-1,3-diamine]-1?4O,N,N?,O?:2?2O,O?;2?2O,O?:3?4O,N,N?,O?-bis(N,N?-dimethylformamide)-1?O,3?O-di-?2-formato-1:2?2O:O?;2:3?2O:O?-trinickel(II)

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dc.contributor.authorYildirim, Leyla Tatar
dc.contributor.authorAtakol, Orhan
dc.contributor.authorKavak, Guelten
dc.date.accessioned2024-04-24T17:08:39Z
dc.date.available2024-04-24T17:08:39Z
dc.date.issued2007
dc.departmentDicle Üniversitesien_US
dc.description.abstractThe title crystal structure, [Ni-3(C19H24N2O2)(2)(CHO2)(2)( C3H7NO)(2)], consists of discrete centrosymmetric homotrinuclear nickel complex molecules. In each molecule, the central Ni-II ion is in a distorted octahedral coordination environment, formed by four O atoms from two chelating DML2- ligands [DMLH2 = N,N'-bis(salicylidene)-2,2'dimethyl- 1,3- propanediamine] in the equatorial plane and two O atoms of two symmetry- related formate ligands in the axial positions. The terminal Ni-II ions also have distorted octahedral coordination environments and these are formed by two O and N atoms from chelating DML2- ligands in the equatorial plane; the axial positions are occupied by O atoms from a dimethylformamide ligand and a formate ligand. The overall result is three edge-shared octahedra in which the closest Ni center dot center dot center dot Ni distance is 3.0857 (14) A. The crystal structure is stabilized by weak C-H center dot center dot center dot O hydrogen bonds ( agnostic interactions).en_US
dc.identifier.doi10.1107/S1600536807040184
dc.identifier.endpageU1419en_US
dc.identifier.issn2056-9890
dc.identifier.scopus2-s2.0-34548419637
dc.identifier.scopusqualityQ3
dc.identifier.startpageM2403en_US
dc.identifier.urihttps://doi.org/10.1107/S1600536807040184
dc.identifier.urihttps://hdl.handle.net/11468/17414
dc.identifier.volume63en_US
dc.identifier.wosWOS:000249759900131
dc.identifier.wosqualityN/A
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoenen_US
dc.publisherInt Union Crystallographyen_US
dc.relation.ispartofActa Crystallographica Section E-Crystallographic Communications
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subject[No Keyword]en_US
dc.titleBis[?2-2,2?-dimethyl-N,N?-bis(2-oxido-benzyl)propane-1,3-diamine]-1?4O,N,N?,O?:2?2O,O?;2?2O,O?:3?4O,N,N?,O?-bis(N,N?-dimethylformamide)-1?O,3?O-di-?2-formato-1:2?2O:O?;2:3?2O:O?-trinickel(II)en_US
dc.titleBis[?2-2,2?-dimethyl-N,N?-bis(2-oxido-benzyl)propane-1,3-diamine]-1?4O,N,N?,O?:2?2O,O?;2?2O,O?:3?4O,N,N?,O?-bis(N,N?-dimethylformamide)-1?O,3?O-di-?2-formato-1:2?2O:O?;2:3?2O:O?-trinickel(II)
dc.typeArticleen_US

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