Synthesis of new boron complexes: application to transfer hydrogenation of acetophenone derivatives

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dc.contributor.authorKılıç, Ahmet
dc.contributor.authorKayan, Cezmi
dc.contributor.authorAydemir, Murat
dc.contributor.authorDurap, Feyyaz
dc.contributor.authorDurgun, Mustafa
dc.contributor.authorBaysal, Akın
dc.contributor.authorTaş, Eşref
dc.contributor.authorGümgüm, Bahattin
dc.contributor.orcid0000-0001-7294-6792
dc.contributor.orcid0000-0003-0899-1948
dc.contributor.orcid0000-0003-3012-7582
dc.contributor.orcid0000-0001-9073-4339
dc.contributor.orcid0000-0001-5700-8546
dc.date.accessioned2024-04-24T15:59:18Z
dc.date.available2024-04-24T15:59:18Z
dc.date.issued2011
dc.departmentDicle Üniversitesi, Fen Fakültesi, Kimya Bölümüen_US
dc.description.abstractTwo new boron complexes were synthesized from N-[3-(methylmercapto)aniline]-3,5-di-tert-butylsalicylaldimine (LH) with boron reagent BPh3 or BF3 center dot Et2O. These boron complexes are stable and easily soluble in protic solvents such as ethanol (C2H5OH) but hardly soluble in nonprotic solvents such as chloroform (CHCl3), dichloromethane (CH2Cl2) and tetrahydrofuran (THF). All new boron complexes have been fully characterized by both analytical and spectroscopic methods. The catalytic activities of complexes [LBPh2], 2, and [LBF2], 3, in the transfer hydrogenation of acetophenone derivatives were tested. Stable boron complexes were found to be efficient catalysts in the transfer hydrogenation of aromatic ketones in good conversions up to 99% in the presence of iso-PrOH/KOH. Copyright (C) 2011 John Wiley & Sons, Ltd.en_US
dc.description.sponsorshipHarran University; Dicle University [DUAPK 05-FF-27]en_US
dc.description.sponsorshipPartial support of this work by Harran University and Dicle University (project number DUAPK 05-FF-27) is gratefully acknowledged.en_US
dc.identifier.citationKılıç, A., Kayan, C., Aydemir, M., Durap, F., Durgun, M., Baysal, A. ve diğerleri. (2011). Synthesis of new boron complexes: Application to transfer hydrogenation of acetophenone derivatives. Applied Organometallic Chemistry, 25(5), 390-394.
dc.identifier.doi10.1002/aoc.1779
dc.identifier.endpage394en_US
dc.identifier.issn0268-2605
dc.identifier.issue5en_US
dc.identifier.scopus2-s2.0-79955041839
dc.identifier.scopusqualityQ1
dc.identifier.startpage390en_US
dc.identifier.urihttps://doi.org/10.1002/aoc.1779
dc.identifier.urihttps://hdl.handle.net/11468/13960
dc.identifier.urihttps://onlinelibrary.wiley.com/doi/epdf/10.1002/aoc.1779
dc.identifier.volume25en_US
dc.identifier.wosWOS:000289515300010
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.institutionauthorKayan, Cezmi
dc.institutionauthorAydemir, Murat
dc.institutionauthorDurap, Feyyaz
dc.institutionauthorBaysal, Akın
dc.institutionauthorGümgüm, Bahattin
dc.language.isoenen_US
dc.publisherWiley-Blackwellen_US
dc.relation.ispartofApplied Organometallic Chemistry
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectBoron complexesen_US
dc.subjectTransfer hydrogenationen_US
dc.subjectBph3en_US
dc.subjectBf3 Center Dot Et2oen_US
dc.subjectSynthesisen_US
dc.titleSynthesis of new boron complexes: application to transfer hydrogenation of acetophenone derivativesen_US
dc.titleSynthesis of new boron complexes: application to transfer hydrogenation of acetophenone derivatives
dc.typeArticleen_US

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