Sonochemical synthesis and characterization of nanostructured copper(I) supramolecular compound as a precursor for the fabrication of pure-phase copper oxide nanoparticles

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dc.contributor.authorRanjbar, Maryam
dc.contributor.authorNabitabar, Masoomeh
dc.contributor.authorCelik, Omer
dc.contributor.authorYousefi, Mostafa
dc.date.accessioned2024-04-24T16:10:38Z
dc.date.available2024-04-24T16:10:38Z
dc.date.issued2015
dc.departmentDicle Üniversitesien_US
dc.description.abstractIn this investigation, nanoparticles and single crystals of a Cu(I) supramolecular compound, [Cu(dmph)-A mu-I](2) (1), [dmph = 2,9-dimethyl-1,10-phenanthroline (neocuproine)], have been synthesized by the reaction of copper(II) acetate, KI and neocuproine as ligand in methanol using sonochemical and heat-gradient methods, respectively. The nanostructure of 1 was characterized by scanning electron microscopy, X-ray powder diffraction, FT-IR spectroscopy and elemental analyses, and the structure of compound 1 was determined by single-crystal X-ray diffraction. The crystal structure of compound 1 has been found to be a binuclear coordination compound. The Cu atoms have slightly distorted tetrahedral geometry with two iodine and two nitrogen coordinated atoms which are trans configuration to each other. Pure phase CuO nanoparticles were simply obtained by calcination of nanosized compound 1 at 700 A degrees C under air atmosphere. This study demonstrates that the supramolecular compounds may be suitable precursors for the simple one-pot preparation of nanoscale metal oxide materials with different and interesting morphologies.en_US
dc.description.sponsorshipIranian National Science Foundation (INSF); Iranian Research Organization for Science and Technology (IROST); Payam-e Noor University; Nanotechnology Initiative Councilen_US
dc.description.sponsorshipAuthors are grateful to Iranian National Science Foundation (INSF) and Iranian Research Organization for Science and Technology (IROST), Payam-e Noor University, and Nanotechnology Initiative Council for their unending effort to provide financial support to undertake this work. Also, the authors are indebted to Dicle University Scientific and Technological Applied and Research Center, Diyarbakir, Turkey, for the use of X-ray diffractometer.en_US
dc.identifier.doi10.1007/s13738-014-0512-9
dc.identifier.endpage559en_US
dc.identifier.issn1735-207X
dc.identifier.issn1735-2428
dc.identifier.issue3en_US
dc.identifier.scopus2-s2.0-84921894342
dc.identifier.scopusqualityQ2
dc.identifier.startpage551en_US
dc.identifier.urihttps://doi.org/10.1007/s13738-014-0512-9
dc.identifier.urihttps://hdl.handle.net/11468/14977
dc.identifier.volume12en_US
dc.identifier.wosWOS:000348383800020
dc.identifier.wosqualityQ3
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoenen_US
dc.publisherSpringeren_US
dc.relation.ispartofJournal of The Iranian Chemical Society
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectSupramolecular Coordination Compounden_US
dc.subjectCrystal Structureen_US
dc.subjectNeocuproineen_US
dc.subjectNanostructureen_US
dc.subjectSonochemical Methoden_US
dc.subjectCopper Oxideen_US
dc.titleSonochemical synthesis and characterization of nanostructured copper(I) supramolecular compound as a precursor for the fabrication of pure-phase copper oxide nanoparticlesen_US
dc.titleSonochemical synthesis and characterization of nanostructured copper(I) supramolecular compound as a precursor for the fabrication of pure-phase copper oxide nanoparticles
dc.typeArticleen_US

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