Rhodium-catalyzed transfer hydrogenation with aminophosphines and analysis of electrical characteristics of rhodium(I) complex/n-Si heterojunctions

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dc.contributor.authorAydemir, Murat
dc.contributor.authorOcak, Yusuf Selim
dc.contributor.authorRafikova, Khadichakhan
dc.contributor.authorKystaubayeva, Nurzhamal
dc.contributor.authorKayan, Cezmi
dc.contributor.authorZazybin, Alexey
dc.contributor.authorOk, Fatih
dc.contributor.authorBaysal, Akın
dc.contributor.authorTemel, Hamdi
dc.date.accessioned2024-04-24T15:59:19Z
dc.date.available2024-04-24T15:59:19Z
dc.date.issued2014
dc.departmentDicle Üniversitesi, Fen Fakültesi, Kimya Bölümüen_US
dc.description.abstractA series of novel neutral mononuclear rhodium(I) complexes of the P?NH ligands have been prepared starting from [Rh(cod)Cl](2) complex. Structural elucidation of the complexes was carried out by elemental analysis, IR and multinuclear NMR spectroscopic data. The complexes were applied to the transfer hydrogenation of acetophenone derivatives to 1-phenylethanol derivatives in the presence of 2-propanol as the hydrogen source. Catalytic studies showed that all complexes are also excellent catalyst precursors for transfer hydrogenation of aryl alkyl ketones in 0.1m iso-PrOH solution. In particular, [Rh(cod)(PPh2NH?C6H4?4-CH(CH3)(2))Cl] acts as an excellent catalyst, giving the corresponding alcohols in excellent conversion up to 99% (turnover frequency588h(-1)). Furthermore, rhodium(I) complexes have been used in the formation of organic-inorganic heterojunction by forming their thin films on n-Si and evaporating Au on the films. It has been seen that the structures have rectifying properties. Their electrical properties have been analyzed with the help of current-voltage measurements. Finally, it has been shown that the complexes can be used in the fabrication of temperature and light sensors. Copyright (c) 2014 John Wiley & Sons, Ltd.en_US
dc.description.sponsorshipDicle University [DUBAP-12-FF-140]en_US
dc.description.sponsorshipPartial support from Dicle University (Project number: DUBAP-12-FF-140) is gratefully acknowledged.en_US
dc.identifier.citationAydemir, M., Ocak, Y. S., Rafikova, K., Kystaubayeva, N., Kayan, C., Zazybin, A. ve diğerleri. (2014). Rhodium-catalyzed transfer hydrogenation with aminophosphines and analysis of electrical characteristics of rhodium(I) complex/n-Si heterojunctions. Applied Organometallic Chemistry, 28(6), 396-404.
dc.identifier.doi10.1002/aoc.3140
dc.identifier.endpage404en_US
dc.identifier.issn0268-2605
dc.identifier.issn1099-0739
dc.identifier.issue6en_US
dc.identifier.scopus2-s2.0-84901192412
dc.identifier.scopusqualityQ1
dc.identifier.startpage396en_US
dc.identifier.urihttps://doi.org/10.1002/aoc.3140
dc.identifier.urihttps://hdl.handle.net/11468/13964
dc.identifier.urihttps://onlinelibrary.wiley.com/doi/epdf/10.1002/aoc.3140
dc.identifier.volume28en_US
dc.identifier.wosWOS:000336440900004
dc.identifier.wosqualityQ1
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.institutionauthorAydemir, Murat
dc.institutionauthorOcak, Yusuf Selim
dc.institutionauthorKayan, Cezmi
dc.institutionauthorOk, Fatih
dc.institutionauthorBaysal, Akın
dc.institutionauthorTemel, Hamdi
dc.language.isoenen_US
dc.publisherWileyen_US
dc.relation.ispartofApplied Organometallic Chemistry
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.subjectAminophosphineen_US
dc.subjectRhodiumen_US
dc.subjectTransfer hydrogenationen_US
dc.subjectHeterojunctionen_US
dc.subjectTemperature sensoren_US
dc.titleRhodium-catalyzed transfer hydrogenation with aminophosphines and analysis of electrical characteristics of rhodium(I) complex/n-Si heterojunctionsen_US
dc.titleRhodium-catalyzed transfer hydrogenation with aminophosphines and analysis of electrical characteristics of rhodium(I) complex/n-Si heterojunctions
dc.typeReview Articleen_US

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