Photochemical reactions of [M(CO)5THF] (M: Cr, Mo and W) with tetradentate Schiff-bases

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dc.contributor.authorKarahan, Senem
dc.contributor.authorKoese, Pelin
dc.contributor.authorSubasi, Elif
dc.contributor.authorTemel, Hamdi
dc.date.accessioned2024-04-24T17:07:49Z
dc.date.available2024-04-24T17:07:49Z
dc.date.issued2008
dc.departmentDicle Üniversitesien_US
dc.description.abstractThe new complexes, [(mu-CO)(2)Cr-2(eta(4)-H2L)(2)], 1; [(mu-CO)M-2(CO)(2)(eta(4)- H2L)(2)], [M=Mo; 2, W; 3]; [(mu-CO)(2)Cr-2(eta(4)-H2L')(2)], 4 and [(mu-CO)M-2(CO)(2)(eta(4)-H2L')(2)], [M=Mo; 5, W; 6] have been synthesized by the photochemical reactions of photogenerated intermediate, M(CO)(5)THF (M=Cr, Mo, W) with two oxygen and nitrogen donor Schiff base ligands, N,N'-bis(2-hydroxynaphtalin-1-carbaldehydene)-1,2-bis(p-aminophenoxy)ethane (H2L) and N,N'-bis(2-hydroxynaphtalin-1-carbaldehydene)-1,4-bis(p-aminophenoxy)butane (H2L'). The complexes have been characterized by elemental analyses, LC-mass spectrometry, magnetic studies, FTIR and H-1-NMR spectroscopy. The spectroscopic studies show that H2L and H2L' ligands are coordinated to the central metal as tetradentate ligands coordinating via their imine N and O donor atoms in (1-6).en_US
dc.identifier.doi10.1080/15533170802254503
dc.identifier.endpage427en_US
dc.identifier.issn1553-3174
dc.identifier.issn1553-3182
dc.identifier.issue5en_US
dc.identifier.scopus2-s2.0-48749121128
dc.identifier.scopusqualityN/A
dc.identifier.startpage422en_US
dc.identifier.urihttps://doi.org/10.1080/15533170802254503
dc.identifier.urihttps://hdl.handle.net/11468/17020
dc.identifier.volume38en_US
dc.identifier.wosWOS:000258052800003
dc.identifier.wosqualityQ4
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoenen_US
dc.publisherTaylor & Francis Incen_US
dc.relation.ispartofSynthesis and Reactivity in Inorganic Metal-Organic and Nano-Metal Chemistry
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectN, N '-Bis(2-Hydroxynaphtalin-1-Carbaldehydene)-1en_US
dc.subject2-Bis(P-Aminophenoxy)Ethaneen_US
dc.subjectN, N '-Bis(2-Hydroxynaphtalin-1-Carbaldehydene)-1en_US
dc.subject4-Bis(P-Aminophenoxy)Butaneen_US
dc.subjectMetal Carbonylsen_US
dc.subjectSchiff Baseen_US
dc.titlePhotochemical reactions of [M(CO)5THF] (M: Cr, Mo and W) with tetradentate Schiff-basesen_US
dc.titlePhotochemical reactions of [M(CO)5THF] (M: Cr, Mo and W) with tetradentate Schiff-bases
dc.typeArticleen_US

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