Coordination chemistry of nickel(II), copper(II), and cobalt(II) with MN4 core-containing two novel vic-dioximes ligands. Synthesis, spectroscopy and redox properties

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dc.contributor.authorKilic A.
dc.contributor.authorTas E.
dc.contributor.authorGumgum B.
dc.contributor.authorYilmaz I.
dc.date.accessioned2024-04-24T18:45:42Z
dc.date.available2024-04-24T18:45:42Z
dc.date.issued2006
dc.departmentDicle Üniversitesien_US
dc.description.abstractTwo new vic-dioxime, N-(4-amino-1-benzyl piperidine)-anti-phenylglyoxime (L1H2) and N-(4-amino-1-benzyl piperidine)-anti-glyoxime (L2H2) were prepared by the reaction of anti-phenylchloroglyoxime and anti-monochloroglyoxime with 4-amino-1-benzyl piperidine in absolute THF at -15°C. Mononuclear nickel(II), copper(II), and cobalt(II) complexes have a metal-ligand ratio of 1:2 in which the ligands coordinate through the two nitrogen atoms as do most vic-dioximes. The ligands and their Co(II), Cu(II), and Ni(II) complexes were characterized by elemental analyses, FT-IR, UV-vis, 1H-NMR and 13C-NMR, magnetic susceptibility measurements, electrical conductivity measurements and cyclic voltammetry. The electrical conductivity of Ni(II), Co(II), and Cu(II) metal complexes were measured using Four-Point Probe analysis. The electrochemical behavior of the Ni(II), Co(II), and Cu(II) complexes were investigated by cyclic voltammetry in DMSO.en_US
dc.identifier.endpage1981en_US
dc.identifier.issn0137-5083
dc.identifier.issue12en_US
dc.identifier.scopus2-s2.0-33846165401
dc.identifier.scopusqualityN/A
dc.identifier.startpage1967en_US
dc.identifier.urihttps://hdl.handle.net/11468/24801
dc.identifier.volume80en_US
dc.indekslendigikaynakScopus
dc.language.isoenen_US
dc.relation.ispartofPolish Journal of Chemistry
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectMetal Complexesen_US
dc.subjectMolar Conductivityen_US
dc.subjectRedox Propertiesen_US
dc.subjectSynthesisen_US
dc.subjectVic-Dioximeen_US
dc.titleCoordination chemistry of nickel(II), copper(II), and cobalt(II) with MN4 core-containing two novel vic-dioximes ligands. Synthesis, spectroscopy and redox propertiesen_US
dc.titleCoordination chemistry of nickel(II), copper(II), and cobalt(II) with MN4 core-containing two novel vic-dioximes ligands. Synthesis, spectroscopy and redox properties
dc.typeArticleen_US

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