Monodisperse palladium nanoparticles supported on chemically derived graphene: highly active and reusable nanocatalysts for Suzuki{Miyaura cross-coupling reactions

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dc.contributor.authorMetin, Önder
dc.contributor.authorDurap, Feyyaz
dc.date.accessioned2024-04-24T19:07:29Z
dc.date.available2024-04-24T19:07:29Z
dc.date.issued2015
dc.departmentDicle Üniversitesien_US
dc.description.abstractAddressed herein is the catalysis of monodisperse palladium nanoparticles (NPs) supported on chemically derived graphene (CDG) for the Suzuki{Miyaura cross-coupling of phenylboronic acid and various aryl halides. Monodis- perse Pd NPs were synthesized by the solution phase reduction of palladium(II) acetylacetonate with morpholine borane complex in oleylamine and deposited on CDG via the liquid phase self-assembly method. Colloidal Pd NPs and CDG-Pd catalyst were characterized by TEM, XRD, SEM, and ICP-MS analyses. The CDG-Pd catalyst showed high activity in the Suzuki{Miyaura cross-couplings of different aryl halides including iodides, bromides, and even chlorides with phenyl- boronic acid under mild conditions. More importantly, the reusability experiments revealed that CDG-Pd catalyst was highly durable by almost maintaining its inherent activity after the 15th catalytic cycle.en_US
dc.identifier.endpage1256en_US
dc.identifier.issn1300-0527
dc.identifier.issn1303-6130
dc.identifier.issue6en_US
dc.identifier.startpage1247en_US
dc.identifier.trdizinid259139en_US
dc.identifier.urihttps://search.trdizin.gov.tr/yayin/detay/259139
dc.identifier.urihttps://hdl.handle.net/11468/27395
dc.identifier.volume39en_US
dc.indekslendigikaynakTR-Dizin
dc.language.isoenen_US
dc.relation.ispartofTurkish Journal of Chemistryen_US
dc.relation.publicationcategoryMakale - Ulusal Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.titleMonodisperse palladium nanoparticles supported on chemically derived graphene: highly active and reusable nanocatalysts for Suzuki{Miyaura cross-coupling reactionsen_US
dc.typeArticleen_US

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