Synthesis, characterization and luminescent properties of silver(I) complexes with 5-sulfosalicylic acid and imidazole derivatives

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dc.contributor.authorÇavuş Kaya, Eda
dc.contributor.authorArslan Biçer, Figen
dc.contributor.authorŞahin, Ertan
dc.contributor.authorYeşilel, Okan Zafer
dc.date.accessioned2025-02-22T14:10:54Z
dc.date.available2025-02-22T14:10:54Z
dc.date.issued2025
dc.departmentDicle Üniversitesien_US
dc.description.abstractThree new Ag(I) coordination compounds, namely, (imH)2[Ag2(μ-Hssal)2(H2O)2] (1), {(2mimH)2[Ag2(μ3-Hssal)2(H2O)2]}n (2) and [Ag2(µ4-Hssal)(dmim)2]n (3) with 5-sulfosalicylic acid (H3ssal) and varying imidazole derivatives (imidazole (im), 2-methylimidazole (2mim), 1,2-dimethylimidazole (dmim)) were synthesized and characterized by IR spectroscopy, elemental analysis, thermal analysis, and single crystal X-ray diffraction techniques. While imidazole and 2-methylimidazole act as counter ions outside the coordination sphere as cations by undergoing proton transfer in complexes 1 and 2, 1,2-dimethylimidazole serves as a ligand in complex 3. Complex 1 is a binuclear compound while complex 2 is two-dimensional (2D) coordination polymer, and complex 3 is one-dimensional (1D) coordination polymer. The complexes 1–3 exhibite ligand-supported argentophilic Ag⋯Ag interactions. The luminescent properties of the complexes are also discussed. © 2025en_US
dc.identifier.doi10.1016/j.poly.2025.117443
dc.identifier.issn0277-5387
dc.identifier.scopus2-s2.0-85217685581en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.urihttps://doi.org/10.1016/j.poly.2025.117443
dc.identifier.urihttps://hdl.handle.net/11468/29872
dc.identifier.volume270en_US
dc.indekslendigikaynakScopus
dc.language.isoenen_US
dc.publisherElsevier Ltden_US
dc.relation.ispartofPolyhedronen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.snmzKA_Scopus_20250222
dc.subject5-Sulfosalicylate complexesen_US
dc.subject5-Sulfosalicylic aciden_US
dc.subjectImidazole complexesen_US
dc.subjectSilver complexesen_US
dc.titleSynthesis, characterization and luminescent properties of silver(I) complexes with 5-sulfosalicylic acid and imidazole derivativesen_US
dc.typeArticleen_US

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