Synthesis of new thiol-derivatized aminophosphines and their catalytic activities in C{C coupling reactions

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dc.contributor.authorMeriç, Nermin
dc.contributor.authorGümgüm, Bahattin
dc.contributor.authorBiricik, Nermin
dc.contributor.authorAzizoğlu, Sevil Şeker
dc.contributor.authorÖzgen, Zeynep
dc.contributor.authorKayan, Cezmi
dc.date.accessioned2024-04-24T19:07:29Z
dc.date.available2024-04-24T19:07:29Z
dc.date.issued2015
dc.departmentDicle Üniversitesien_US
dc.description.abstractA series of new aminophosphines [Ph 2 PHN-C 6 H 4 -R, where R = o -SH ( 4a ), m -SH ( 4b) or p -SH ( 4c )] were readily synthesized from cheap starting materials by the phosphorylation reaction of o , m , and p -aminothiophenols with Ph 2 PCl in the presence of triethyl amine. The new compounds were characterized by NMR and IR spectroscopy and microanalysis. In addition, aminophosphine ligands{palladium systems were investigated as precatalysts in C{C coupling reactions. Compounds 4b and 4c were proved to be excellent catalysts for Suzuki and Heck cross-coupling reactions.en_US
dc.identifier.endpage1264en_US
dc.identifier.issn1300-0527
dc.identifier.issn1303-6130
dc.identifier.issue6en_US
dc.identifier.startpage1257en_US
dc.identifier.trdizinid259140
dc.identifier.urihttps://search.trdizin.gov.tr/yayin/detay/259140
dc.identifier.urihttps://hdl.handle.net/11468/27394
dc.identifier.volume39en_US
dc.indekslendigikaynakTR-Dizin
dc.language.isoenen_US
dc.relation.ispartofTurkish Journal of Chemistry
dc.relation.publicationcategoryMakale - Ulusal Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.titleSynthesis of new thiol-derivatized aminophosphines and their catalytic activities in C{C coupling reactionsen_US
dc.titleSynthesis of new thiol-derivatized aminophosphines and their catalytic activities in C{C coupling reactions
dc.typeArticleen_US

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