New Pd(II) and Pt(II)-diaminophosphine complexes bearing cyclohexyl or isopropyl moiety: use of Pd(II) complexes as precatalyst in Mizoroki{Heck and Suzuki{Miyaura cross-coupling reactions

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dc.contributor.authorBaysal, Akın
dc.contributor.authorDurap, Feyyaz
dc.contributor.authorAydemir, Murat
dc.date.accessioned2024-04-24T19:07:29Z
dc.date.available2024-04-24T19:07:29Z
dc.date.issued2015
dc.departmentDicle Üniversitesien_US
dc.description.abstractTwo new diaminophosphine ligands, N , N '-bis(dicyclohexylphosphino)-2-(aminomethyl)aniline ( 1 ) and N , N '-bis(diisopropylphosphino)-2-(aminomethyl)aniline ( 2 ) were synthesized by the reaction of 2-(aminomethyl)aniline with two equivalents of Cy 2 PCl or (iPr) 2 PCl, respectively. The reactions of 1 and 2 with MCl 2 (cod) (M = Pd, Pt; cod = 1,5-cyclooctadiene) yield complexes [ cis -Pd(L 2 P NHC 6 H 4 CH 2 NH P L 2 )Cl 2 ] (L = Cy 3 , iPr 4 ) and [ cis - Pt(L 2 P NHC 6 H 4 CH 2 NH P L 2 )Cl 2 ] (L = Cy 5 , iPr 6 ), respectively. The catalytic activity of the palladium complexes was investigated in the Suzuki{Miyaura cross-coupling reaction in the presence of Cs 2 CO 3 as a base. The palladium complexes were also found to be highly active catalysts in the Mizoroki{Heck reaction.en_US
dc.identifier.endpage1288en_US
dc.identifier.issn1300-0527
dc.identifier.issn1303-6130
dc.identifier.issue6en_US
dc.identifier.startpage1279en_US
dc.identifier.trdizinid259142en_US
dc.identifier.urihttps://search.trdizin.gov.tr/yayin/detay/259142
dc.identifier.urihttps://hdl.handle.net/11468/27393
dc.identifier.volume39en_US
dc.indekslendigikaynakTR-Dizin
dc.language.isoenen_US
dc.relation.ispartofTurkish Journal of Chemistryen_US
dc.relation.publicationcategoryMakale - Ulusal Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.titleNew Pd(II) and Pt(II)-diaminophosphine complexes bearing cyclohexyl or isopropyl moiety: use of Pd(II) complexes as precatalyst in Mizoroki{Heck and Suzuki{Miyaura cross-coupling reactionsen_US
dc.typeArticleen_US

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