NOVEL MONONUCLEAR METAL-PHOSPHINITE COMPOUNDS AND CATALYTIC PERFORMANCE IN TRANSFER HYDROGENATION OF KETONES

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dc.contributor.authorMeriç, Nermin
dc.contributor.authorAydemir, Murat
dc.contributor.authorIşık, Uğur
dc.date.accessioned2024-04-24T19:13:16Z
dc.date.available2024-04-24T19:13:16Z
dc.date.issued2022
dc.departmentDicle Üniversitesien_US
dc.description.abstractSince the obtained chiral alcohols are rather useful as well as biologically active compounds, reduction of ketones to their respective alcohols is a crucial topic in synthetic chemistry. Thus, a new phosphinite ligand was synthesized by the interaction of cationic species N-vinyl imidazolium (1) with PCy2Cl. This phosphinite ligand in combination with [Ru(?6-p-cymene)(µ-Cl)Cl]2 and Ir(?5-C5Me5)(?-Cl)Cl]2 gave active catalytic systems for transfer hydrogenation reaction. Under optimum circumstances, ruthenium complex (3) showed rather high conversion reduction reaction of acetophenone. Reversibility of the transfer hydrogenation reaction was found to be low under these reaction circumstances.en_US
dc.identifier.doi10.51477/mejs.1077805
dc.identifier.endpage15en_US
dc.identifier.issn2618-6136
dc.identifier.issue1en_US
dc.identifier.startpage1en_US
dc.identifier.trdizinid1102373
dc.identifier.urihttps://doi.org/10.51477/mejs.1077805
dc.identifier.urihttps://search.trdizin.gov.tr/yayin/detay/1102373
dc.identifier.urihttps://hdl.handle.net/11468/28499
dc.identifier.volume8en_US
dc.indekslendigikaynakTR-Dizin
dc.language.isoenen_US
dc.relation.ispartofMiddle East Journal of Science
dc.relation.publicationcategoryMakale - Ulusal Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.titleNOVEL MONONUCLEAR METAL-PHOSPHINITE COMPOUNDS AND CATALYTIC PERFORMANCE IN TRANSFER HYDROGENATION OF KETONESen_US
dc.titleNOVEL MONONUCLEAR METAL-PHOSPHINITE COMPOUNDS AND CATALYTIC PERFORMANCE IN TRANSFER HYDROGENATION OF KETONES
dc.typeArticleen_US

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