Investigation of some 1-3-diols for the requirements of solvent extraction of boron: 2,2,6-trimethyl-1,3 heptanediol as a potential boron extractant

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dc.contributor.authorHoşgören, Halil
dc.contributor.authorTural, Servet
dc.contributor.authorTural, Bilsen
dc.date.accessioned2024-04-24T19:01:29Z
dc.date.available2024-04-24T19:01:29Z
dc.date.issued2007
dc.departmentDicle Üniversitesien_US
dc.description.abstractEighteen 1,3-diols were synthesized and their structure and distribution ratio for the solvent extraction of boron were studied. Diols with a high distribution ratio $(D_{B(OH)_3} > 10)$ were investigated for the requirements of solvent extraction of boron. Their extraction capacity, and solubility in aqueous phase and in organic diluents were investigated by comparison to -ethyl-1,3-hexanediol (EHD), which is widely used as a boron extractant. Among a series of 1,3 diols, 1-benzyl-2,2-dimethyl-1,3-propanediol (4a) and 2,2,6-trimethyl-1,3-heptanediol (3a) were found to have very low solubility in the aqueous phase compared to the others. IPD (3a) was found to have a high solubility in aliphatic diluents such as kerosene. IPD,which has good solubility properties for the solvent extraction of boron, was studied in detail, including dependence of pH, diol concentration, and stripping facility, and in various organic diluents.en_US
dc.identifier.endpage170en_US
dc.identifier.issn1300-0527
dc.identifier.issn1303-6130
dc.identifier.issue2en_US
dc.identifier.startpage163en_US
dc.identifier.trdizinid67312
dc.identifier.urihttps://search.trdizin.gov.tr/yayin/detay/67312
dc.identifier.urihttps://hdl.handle.net/11468/26306
dc.identifier.volume31en_US
dc.indekslendigikaynakTR-Dizin
dc.language.isoenen_US
dc.relation.ispartofTurkish Journal of Chemistry
dc.relation.publicationcategoryMakale - Ulusal Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.titleInvestigation of some 1-3-diols for the requirements of solvent extraction of boron: 2,2,6-trimethyl-1,3 heptanediol as a potential boron extractanten_US
dc.titleInvestigation of some 1-3-diols for the requirements of solvent extraction of boron: 2,2,6-trimethyl-1,3 heptanediol as a potential boron extractant
dc.typeArticleen_US

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