Synthesis, spectroscopic and electrochemical studies of novel transition metal complexes with N,N'-bis(2-hydroxynaphthalin-1-carbaldehydene)-1,3-bis-(o- aminophenoxy)propane

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dc.contributor.authorTemel H.
dc.contributor.authorIlhan S.
dc.contributor.authorAslanoglu M.
dc.contributor.authorAlp H.
dc.date.accessioned2024-04-24T18:45:40Z
dc.date.available2024-04-24T18:45:40Z
dc.date.issued2007
dc.departmentDicle Üniversitesien_US
dc.description.abstractA novel Schiff base obtained by the reaction of 1,3-bis-(o-aminophenoxy) propane and 2-hydroxynaphthalin-1-carbaldehyde, forms complexes with Co(II), Cu(II) and Ni(II). The Schiff base ligand and its metal complexes have been characterized by elemental analysis, microanalytical data, magnetic measurements, UV-visible, 1H NMR, 13C NMR and IR-spectra as well as conductance measurements. Electrochemical data show that NiL and CuL complexes undergo metal based quasi-reversible one-electron redox processes. However, metal complexes also exhibit ligand based irreversible redox waves. The electrochemical results also indicate that the electron transfer rate is higher for NiL complex than the CuL complex. Voltammetric data reveal easier electron donor properties for the NiL complex.en_US
dc.identifier.endpage1112en_US
dc.identifier.issn0376-4710
dc.identifier.issue7en_US
dc.identifier.scopus2-s2.0-34548314383
dc.identifier.scopusqualityQ4
dc.identifier.startpage1109en_US
dc.identifier.urihttps://hdl.handle.net/11468/24773
dc.identifier.volume46en_US
dc.indekslendigikaynakScopus
dc.language.isoenen_US
dc.relation.ispartofIndian Journal of Chemistry - Section A Inorganic, Physical, Theoretical and Analytical Chemistry
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.titleSynthesis, spectroscopic and electrochemical studies of novel transition metal complexes with N,N'-bis(2-hydroxynaphthalin-1-carbaldehydene)-1,3-bis-(o- aminophenoxy)propaneen_US
dc.titleSynthesis, spectroscopic and electrochemical studies of novel transition metal complexes with N,N'-bis(2-hydroxynaphthalin-1-carbaldehydene)-1,3-bis-(o- aminophenoxy)propane
dc.typeArticleen_US

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