Coordination chemistry of nickel(II), copper(II), and cobalt(II) with MN4 core-containing two novel vic-dioximes ligands.: Synthesis, spectroscopy and redox properties

Basit Öğe Kaydı
dc.contributor.authorKilic, A.
dc.contributor.authorTas, E.
dc.contributor.authorGumgum, B.
dc.contributor.authorYilmaz, I.
dc.date.accessioned2024-04-24T17:48:13Z
dc.date.available2024-04-24T17:48:13Z
dc.date.issued2006
dc.departmentDicle Üniversitesien_US
dc.description.abstractTwo new vic-dioxime, N-(4-amino-1-benzylpiperidine)-anti-phenylglyoxime(1,1142) and N-(4-amino-1-benzyl piperidine)-anti-glyoxime (L2H2)were prepared by the reaction of anti-phenylchloroglyoxime and anti-monochloroglyoxime with 4-amino1-benzyl piperidine in absolute THF at -15 degrees C. Mononuclear nickel(II), copper(H), and cobalt(H) complexes have a metal-ligand ratio of 1:2 in which the ligands coordinate through the two nitrogen atoms as do most vic-dioximes. The ligands and their Co(II), Cu(II), and Ni(II) complexes were characterized by elemental analyses, FT-IR, UV-vis, H-1-NMR and C-13-NMR, magnetic susceptibility measurements, electrical conductivity measurements and cyclic voltammetry. The electrical conductivity of Ni(II), Co(II), and Cu(II) metal complexes were measured using Four-Point Probe analysis. The electrochemical behavior of the Ni(II), Co(II), and Cu(II) complexes were investigated by cyclic voltammetry in DMSO.en_US
dc.identifier.endpage1981en_US
dc.identifier.issn0137-5083
dc.identifier.issue12en_US
dc.identifier.startpage1967en_US
dc.identifier.urihttps://hdl.handle.net/11468/22932
dc.identifier.volume80en_US
dc.identifier.wosWOS:000243205500004
dc.identifier.wosqualityQ4
dc.indekslendigikaynakWeb of Science
dc.language.isoenen_US
dc.publisherPolish Chemical Socen_US
dc.relation.ispartofPolish Journal of Chemistry
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectVic-Dioximeen_US
dc.subjectMetal Complexesen_US
dc.subjectSynthesisen_US
dc.subjectRedox Propertiesen_US
dc.subjectMolar Conductivityen_US
dc.titleCoordination chemistry of nickel(II), copper(II), and cobalt(II) with MN4 core-containing two novel vic-dioximes ligands.: Synthesis, spectroscopy and redox propertiesen_US
dc.titleCoordination chemistry of nickel(II), copper(II), and cobalt(II) with MN4 core-containing two novel vic-dioximes ligands.: Synthesis, spectroscopy and redox properties
dc.typeArticleen_US

Dosyalar

Koleksiyon

WoS İndeksli Yayınlar Koleksiyonu