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Readily available ferrocenyl-phosphinite ligands for Ru(II)-catalyzed enantioselective transfer hydrogenation of ketones and fabrication of hybrid heterojunctions
(Elsevier Science Sa, 2014)
A variety of phosphinite based on ferrocenyl moiety possessing central chirality have been screened as ligands for ruthenium(II)-catalyzed transfer hydrogenation of acetophenone derivatives using iso-PrOH as the hydrogen ...
Transfer hydrogenation of ketones catalyzed by new rhodium and iridium complexes of aminophosphine containing cyclohexyl moiety and photosensing behaviors of rhodium and iridium based devices
(Elsevier Science Sa, 2014)
The reaction of [Rh(mu-Cl)(cod)](2) and Ir(eta(5)-C5Me5)(mu-Cl)Cl](2) with aminophosphine ligands Cy2PNHCH2-C4H3X (X: O; S) gave a range of new monodendate [Rh(Cy(2)PNHCH(2)eC(4)H(3)O)(cod) Cl], (1), [Rh(Cy(2)PNHCH(2)eC( ...
Tunable ferrocenyl-phosphinite ligands for the ruthenium(II)-catalyzed asymmetric transfer hydrogenation of ketones
(Elsevier, 2013)
We report here new examples of enantiomerically pure monodendate phosphinite ligands containing both a ferrocene moiety and NH bridging moiety adjacent to the stereocenter, as well as their ruthenium(II) dichloro complexes. ...
