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Readily available ferrocenyl-phosphinite ligands for Ru(II)-catalyzed enantioselective transfer hydrogenation of ketones and fabrication of hybrid heterojunctions

Ak, Bunyamin; Aydemir, Murat; Ocak, Yusuf Selim; Durap, Feyyaz; Kayan, Cezmi; Baysal, Akin; Temel, Hamdi (Elsevier Science Sa, 2014)

A variety of phosphinite based on ferrocenyl moiety possessing central chirality have been screened as ligands for ruthenium(II)-catalyzed transfer hydrogenation of acetophenone derivatives using iso-PrOH as the hydrogen ...

Transfer hydrogenation of ketones catalyzed by new rhodium and iridium complexes of aminophosphine containing cyclohexyl moiety and photosensing behaviors of rhodium and iridium based devices

Rafikova, Khadichakhan; Kystaubayeva, Nurzhamal; Aydemir, Murat; Kayan, Cezmi; Ocak, Yusuf Selim; Temel, Hamdi; Zazybin, Alexey (Elsevier Science Sa, 2014)

The reaction of [Rh(mu-Cl)(cod)](2) and Ir(eta(5)-C5Me5)(mu-Cl)Cl](2) with aminophosphine ligands Cy2PNHCH2-C4H3X (X: O; S) gave a range of new monodendate [Rh(Cy(2)PNHCH(2)eC(4)H(3)O)(cod) Cl], (1), [Rh(Cy(2)PNHCH(2)eC( ...

Rhodium-catalyzed transfer hydrogenation with aminophosphines and analysis of electrical characteristics of rhodium(I) complex/n-Si heterojunctions

Aydemir, Murat; Ocak, Yusuf Selim; Rafikova, Khadichakhan; Kystaubayeva, Nurzhamal; Kayan, Cezmi; Zazybin, Alexey; Ok, Fatih; Baysal, Akın; Temel, Hamdi (Wiley, 2014)

A series of novel neutral mononuclear rhodium(I) complexes of the P?NH ligands have been prepared starting from [Rh(cod)Cl](2) complex. Structural elucidation of the complexes was carried out by elemental analysis, IR and ...

Novel cyclohexyl-based aminophosphine ligands and use of their Ru(II) complexes in transfer hydrogenation of ketones

Kayan, Cezmi; Meriç, Nermin; Aydemir, Murat; Ocak, Yusuf Selim; Baysal, Akın; Temel, Hamdi (Wiley, 2014)

Two new aminophosphines - furfuryl-(N-dicyclohexylphosphino)amine, [Cy2PNHCH2-C4H3O] (1) and thiophene-(N-dicyclohexylphosphino)amine, [Cy2PNHCH2-C4H3S] (2) - were prepared by the reaction of chlorodicyclohexylphosphine ...

Cross-coupling reactions in water using ionic liquid-based palladium(II)-phosphinite complexes as outstanding catalysts

Meriç, Nermin; Aydemir, Murat; Işık, Uğur; Ocak, Yusuf Selim; Rafikova, Khadichakhan; Paşa, Salih; Kayan, Cezmi; Durap, Feyyaz; Temel, Hamdi; Zazybin, Alexey G. (Wiley, 2014)

Two new phosphinite ligands based on ionic liquids [(Ph2PO)C7H14N2Cl]Cl (1) and [(Cy2PO)C7H14N2Cl]Cl (2) were synthesized by reaction of 1-(3-chloro-2-hydoxypropyl)-3-methylimidazolium chloride, [C7H15N2OCl]Cl, with one ...