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Öğe Desulfurization and deashing of Hazro coal via a flotation method(Amer Chemical Soc, 2005) Ayhan, FD; Abakay, H; Saydut, AIn this study, desulfurization and deashing of Hazro coal via a flotation method were studied. For this purpose, experimental studies were conducted on the coal sample with ash, sulfur, volatile matter, and fixed carbon contents of 24.77%, 6.90%, 35.18%, and 38.06%, respectively, and two groups of flotation experiments were made. The effects of pH, collector amount, and various frothers (MIBC, AF 76, pine oil, DF 250) on the depressing and floating pyrite from Hazro coal were investigated in the first and second group flotation experiments, respectively. Flotation results indicated that, when compared to various frothers, the following order for the depressing of pyrite was obtained: MIBC > pine oil > AF 76 > DF 250. For the floating of pyrite, the following order was obtained: DF 250 > pine oil > AF 76 > MIBC. A concentrate containing 1.12% pyritic sulfur and 13.02% ash with a pyritic sulfur reduction of 66.86% was obtained from a feed that contained 4.95% pyritic sulfur and 24.77% ash. The flotation method removed most of the sulfate sulfur (> 90%) and 66.86% of the pyritic sulfur from the coal sample.Öğe Elemental composition of Southeastern Anatolia asphaltites (Turkey) as a function of particle size(Estonian Academy Publishers, 2003) Hamamci, C; Düz, MZ; Saydut, A; Merdivan, MElemental composition of asphaltites from Southeastern Anatolia was determined after grinding the samples and separating particles obtained into fractions by sieving. The total content of carbon, hydrogen, nitrogen and sulfur was highest in Halbur asphaltite where they were present over a wide size range (from 125 to 600 mum). The content of nitrogen, the least element in asphaltites, did not depend on grain size, whereas the carbon and sulfur concentrations increased with increasing size.Öğe Pyrolysis kinetics and chemical composition of Hazro coal according to the particle size(Springer, 2005) Duz, MZ; Tonbul, Y; Baysal, A; Akba, O; Saydut, A; Hamamci, CThe relationship between particle size and chemical composition of Hazro coal (origin: SE Anatolia, Turkey) has been examined by elemental analysis and by thermogravimetric pyrolysis. The chemical composition of the coal was determined by grinding sample particles physically and separating according to their size in mm by sieving. Particle size distribution of the coal and chemical composition of these fractions were given. The coal has been non-isothermally pyrolysed in a thermogravimetric analyser to determine the kinetic factors. Thermal gravimetric (TG/DTG) experiments were performed from ambient temperature to 800 degrees C under a nitrogen atmosphere at heating rate 10 K min(-1) with five different particle size ranges. Kinetic parameters of the samples were determined using a Coats and Redfern kinetic model, assuming a first-order reaction. Depending on the particle size of the coal samples, the mean activation energy values varied between 49.1 and 84.6 kJ mol(-1). The results discussed indicate that activation energies increase as the particle size decreases.