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Öğe Assessment of the Relationship Between Humic Acid Contents and Trace Elements of Some Agricultural Soils in Diyarbakır Region by Multivariate Statistical Methods(Kahramanmaras Sutcu Imam Univ Rektorlugu, 2024) Duzgun, Mehmet; Eren, Abdullah; Bilge, Ugur; Ceylan, Ramazan; Selcuk, Ramazan; Duz, M. ZahirThere are important relationships between humic acid (HA) and the bioavailability, reactions and mobility of trace elements in the soil. For this reason, soils are tried to be improved chemically, biologically and physically with HA applications. In this study, the relationship of humic acid contents of 118 agricultural soil samples from Diyarbakir region with some trace elements (Al, As, Ba, Be, Cd, Fe, Mn, Pb, Sb, Sn, Se, V and P) was evaluated by multivariate statistical analysis. After the soil samples were solubilized by the microwave wet digestion method, the element contents were determined with the ICP OES (Inductively Coupled Plasma Optical Emission Spectrometer) device. SRM NIST 2586 was used as SRM (Standard Reference Material) for the accuracy of the method. Recovery values were found between 91.6% and 105.9% as a result of the analysis. Humic acid was extracted from soils by the International Society for Humic Substances (IHSS) method and determined using a shaker and centrifuge device. For the accuracy of the method, it was tested with Humic Acid Sodium Salt (HA-Na). Pearson correlation and partial correlation analysis were applied to the obtained data set. In addition, multivariate statistical analyses such as multiple regression HCA (Hierarchical Cluster Analysis) and PCA (Principal Component Analysis) were applied. Multiple regression analysis was performed according to the Step-wise method. Manganese and P (p< 0.01) were significant when HA was taken as the dependent variable. According to the Pearson correlation coefficient, the correlation between HA and As (r = -0.282**) in soil was negative and significant, while Fe (r = 0.185*), Mn (r = 0.273**)), Sn (r = 0.242*), Se (r = 0.325**) and P (r = 0.315**) were determined as positive and significant. In clustering and PCA analysis, HA, P Mn and Fe were found to be in the same group. The analyses have shown that HA has a positive effect on the plant nutrients in the soil.Öğe ICP-OES Multi-element Analysis of Wheat Grown in Southeastern Turkey(Atomic Spectroscopy Press Ltd, 2017) Duz, M. Zahir; Duzgun, Mehmet; Cam, Belgizar; Celik, K. Serdar; Kilinc, ErsinThe bread and durum wheat varieties grown in Southeastern Turkey are the main source of food consumed by the Turkish population and serve as bread and pasta. In this study, 12 kinds of durum wheat and 5 kinds of bread wheat samples registered by the International Agricultural Research and Training Centre of Turkey (IARTC, Turkey) were investigated for their multi-elemental concentrations (Ca, K, Mg, Fe, Zn, Mn, Si, Sn, Cu, Cr, Cd, Ni, V, Pb, As, and Se). The samples were microwave digested and the elements determined by ICP-OES. The results were in good agreement with the certified values. This study shows that the elements Si, Fe, Zn, Cd, Cr, Cu, Sn, and Pb in durum wheat were higher than in bread wheat. Both wheat species were found to be rich in terms of Ca, Mg, and K. The multi-element content of some bread wheat and durum wheat was also in good agreement with the maximum allowable levels of the Food and Agriculture Organization (FAO) World Health (WHO).